Synthesis and X-ray crystal structure of [P2(μ-H)(μ-S)(dppe)2]+, a diplatinum cation with hydrido and sulphido ligands bridging a PtPt bond

Mercè Capdevila, Pilar González-Duarte, Ignasi Mira, Joan Sola, William Clegg

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12 Citations (Scopus)

Abstract

Reaction of [Pt(SC5H9NMe)2(dppe)] with [PtCl2(dppe)] in organic solutions containing small amounts of phosgene as an impurity gives the cation [Pt2(μ-H)(μ-S)(dppe)2]+. The product is characterized by X-ray crystallography and the hydrido bridge by NMR spectroscopy. © 1992.
Original languageEnglish
Pages (from-to)3091-3093
JournalPolyhedron
Volume11
Issue number23
DOIs
Publication statusPublished - 1 Jan 1992

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