Synthesis and vibrational spectra of[RSHgII]2+(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate.

Heribert Barrera; Joan Carles Bayon; Pilar Gonzalez-Duarte; Joan Sola; Josep M. Viñas; Jose Luis Briansó; Marie Claire Briansó; Xavier Solans

doi:10.1016/S0277-5387(00)80862-1

Synthesis and vibrational spectra of[RSHgII]2+(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate.

Heribert Barrera, Joan Carles Bayon, Pilar Gonzalez-Duarte, Joan Sola, Josep M. Viñas, Jose Luis Briansó, Marie Claire Briansó, Xavier Solans

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

46 Citations (Scopus)

Abstract

Hg(II) complexes have been prepared with γ-mercaptoamine ligands 1-methyl-4-mercaptopiperidine (4-MP), 1-methyl-3(mercaptomethyl)piperidine (3-MMP) and 1-methyl-2(2-mercaptoethyl)piperidine (2-MEP) with 1:1 and 1:2 metal to ligand ratios. Infrared and Raman spectra for all these compounds have been recorded and discussed. The spectral features agree with a linear SHgS structure and with the characteristic two-coordination of mercury in all the complexes. The structure of [Hg(4-MP)2](ClO4)2 has been determined by X-ray crystallography. The crystals are orthorhombic, space group C2221 (Z=4) in a unit cell of dimensions a= 13.161 (3) Å, b= 6.589 (2) Å and c= 24.740 (4) Å. Solution of the structure by direct methods led to a final weighted R factor of 0.057 for 1339 independent reflections. The crystal structure consists of discrete [Hg(4-MP)2]2+ cations and ClO4- anions packed in layers paralell to the (100) plane. © 1982.

Original language	English
Pages (from-to)	647-654
Journal	Polyhedron
Volume	1
Issue number	7-8
DOIs	https://doi.org/10.1016/S0277-5387(00)80862-1
Publication status	Published - 1 Jan 1982

Access to Document

10.1016/S0277-5387(00)80862-1

Fingerprint Dive into the research topics of 'Synthesis and vibrational spectra of[RSHgII]2+(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate.'. Together they form a unique fingerprint.

Cite this

Barrera, H., Bayon, J. C., Gonzalez-Duarte, P., Sola, J., Viñas, J. M., Briansó, J. L., Briansó, M. C., & Solans, X. (1982). Synthesis and vibrational spectra of[RSHgII]2+(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate. Polyhedron, 1(7-8), 647-654. https://doi.org/10.1016/S0277-5387(00)80862-1

Barrera, Heribert ; Bayon, Joan Carles ; Gonzalez-Duarte, Pilar ; Sola, Joan ; Viñas, Josep M. ; Briansó, Jose Luis ; Briansó, Marie Claire ; Solans, Xavier. / Synthesis and vibrational spectra of[RSHgII]2+(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate. In: Polyhedron. 1982 ; Vol. 1, No. 7-8. pp. 647-654.

@article{3d5ce0ecba124a8296282763ddc5b743,

title = "Synthesis and vibrational spectra of[RSHgII]2+(ClO4)2 complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate.",

abstract = "Hg(II) complexes have been prepared with γ-mercaptoamine ligands 1-methyl-4-mercaptopiperidine (4-MP), 1-methyl-3(mercaptomethyl)piperidine (3-MMP) and 1-methyl-2(2-mercaptoethyl)piperidine (2-MEP) with 1:1 and 1:2 metal to ligand ratios. Infrared and Raman spectra for all these compounds have been recorded and discussed. The spectral features agree with a linear SHgS structure and with the characteristic two-coordination of mercury in all the complexes. The structure of [Hg(4-MP)2](ClO4)2 has been determined by X-ray crystallography. The crystals are orthorhombic, space group C2221 (Z=4) in a unit cell of dimensions a= 13.161 (3) {\AA}, b= 6.589 (2) {\AA} and c= 24.740 (4) {\AA}. Solution of the structure by direct methods led to a final weighted R factor of 0.057 for 1339 independent reflections. The crystal structure consists of discrete [Hg(4-MP)2]2+ cations and ClO4- anions packed in layers paralell to the (100) plane. {\textcopyright} 1982.",

author = "Heribert Barrera and Bayon, {Joan Carles} and Pilar Gonzalez-Duarte and Joan Sola and Vi{\~n}as, {Josep M.} and Brians{\'o}, {Jose Luis} and Brians{\'o}, {Marie Claire} and Xavier Solans",

year = "1982",

month = jan,

day = "1",

doi = "10.1016/S0277-5387(00)80862-1",

language = "English",

volume = "1",

pages = "647--654",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "7-8",

}

Barrera, H, Bayon, JC, Gonzalez-Duarte, P, Sola, J, Viñas, JM, Briansó, JL, Briansó, MC & Solans, X 1982, 'Synthesis and vibrational spectra of[RSHgII]2+(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate.', Polyhedron, vol. 1, no. 7-8, pp. 647-654. https://doi.org/10.1016/S0277-5387(00)80862-1

Synthesis and vibrational spectra of[RSHgII]2+(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate. / Barrera, Heribert; Bayon, Joan Carles; Gonzalez-Duarte, Pilar; Sola, Joan; Viñas, Josep M.; Briansó, Jose Luis; Briansó, Marie Claire; Solans, Xavier.

In: Polyhedron, Vol. 1, No. 7-8, 01.01.1982, p. 647-654.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Synthesis and vibrational spectra of[RSHgII]2+(ClO4)2 complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate.

AU - Barrera, Heribert

AU - Bayon, Joan Carles

AU - Gonzalez-Duarte, Pilar

AU - Sola, Joan

AU - Viñas, Josep M.

AU - Briansó, Jose Luis

AU - Briansó, Marie Claire

AU - Solans, Xavier

PY - 1982/1/1

Y1 - 1982/1/1

N2 - Hg(II) complexes have been prepared with γ-mercaptoamine ligands 1-methyl-4-mercaptopiperidine (4-MP), 1-methyl-3(mercaptomethyl)piperidine (3-MMP) and 1-methyl-2(2-mercaptoethyl)piperidine (2-MEP) with 1:1 and 1:2 metal to ligand ratios. Infrared and Raman spectra for all these compounds have been recorded and discussed. The spectral features agree with a linear SHgS structure and with the characteristic two-coordination of mercury in all the complexes. The structure of [Hg(4-MP)2](ClO4)2 has been determined by X-ray crystallography. The crystals are orthorhombic, space group C2221 (Z=4) in a unit cell of dimensions a= 13.161 (3) Å, b= 6.589 (2) Å and c= 24.740 (4) Å. Solution of the structure by direct methods led to a final weighted R factor of 0.057 for 1339 independent reflections. The crystal structure consists of discrete [Hg(4-MP)2]2+ cations and ClO4- anions packed in layers paralell to the (100) plane. © 1982.

AB - Hg(II) complexes have been prepared with γ-mercaptoamine ligands 1-methyl-4-mercaptopiperidine (4-MP), 1-methyl-3(mercaptomethyl)piperidine (3-MMP) and 1-methyl-2(2-mercaptoethyl)piperidine (2-MEP) with 1:1 and 1:2 metal to ligand ratios. Infrared and Raman spectra for all these compounds have been recorded and discussed. The spectral features agree with a linear SHgS structure and with the characteristic two-coordination of mercury in all the complexes. The structure of [Hg(4-MP)2](ClO4)2 has been determined by X-ray crystallography. The crystals are orthorhombic, space group C2221 (Z=4) in a unit cell of dimensions a= 13.161 (3) Å, b= 6.589 (2) Å and c= 24.740 (4) Å. Solution of the structure by direct methods led to a final weighted R factor of 0.057 for 1339 independent reflections. The crystal structure consists of discrete [Hg(4-MP)2]2+ cations and ClO4- anions packed in layers paralell to the (100) plane. © 1982.

U2 - 10.1016/S0277-5387(00)80862-1

DO - 10.1016/S0277-5387(00)80862-1

M3 - Article

VL - 1

SP - 647

EP - 654

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 7-8

ER -

Synthesis and vibrational spectra of[RSHg<sup>II</sup>]<sup>2+</sup>(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate.

Abstract

Access to Document

Fingerprint Dive into the research topics of 'Synthesis and vibrational spectra of[RSHg<sup>II</sup>]<sup>2+</sup>(ClO<inf>4</inf>)<inf>2</inf> complexes. Crystal and molecular structure of bis(N-methylpiperidinium-4-thiolato)-mercury(II) perchlorate.'. Together they form a unique fingerprint.

Cite this