Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe2(CO)6(μ-PPh2(μ-CPhCPhH)]

Ramón Yáñez; Josep Ros; René Mathieu; Xavier Solans; Mercé Font-Bardia

doi:10.1016/0022-328X(90)85413-S

Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe₂(CO)₆(μ-PPh₂(μ-CPhCPhH)]

Ramón Yáñez, Josep Ros, René Mathieu, Xavier Solans, Mercé Font-Bardia

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

17 Citations (Scopus)

Abstract

Treatment of [Fe2(CO)6(μ-CO)(μ-CRCR′H)]- (R = R′ = Ph, H an RPh, R′ = Me) with PPh2Cl in CH2Cl2 in the presence of TlBF4 gives complexes of the type [Fe2(CO)6(μ-PPh2)(μ-CRCR′H) ], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe2(CO)6(μ-CO)(μ-PPh2)]- with CF3COOH and acetylenes. The crystal structure of the complex [Fe2(CO)6(μ-PPh2)(μ-CPHCPhH)] is reported. © 1990.

Original language	English
Pages (from-to)	219-226
Journal	Journal of Organometallic Chemistry
Volume	389
Issue number	2
DOIs	https://doi.org/10.1016/0022-328X(90)85413-S
Publication status	Published - 12 Jun 1990

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title = "Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe2(CO)6(μ-PPh2(μ-CPhCPhH)]",

abstract = "Treatment of [Fe2(CO)6(μ-CO)(μ-CRCR′H)]- (R = R′ = Ph, H an RPh, R′ = Me) with PPh2Cl in CH2Cl2 in the presence of TlBF4 gives complexes of the type [Fe2(CO)6(μ-PPh2)(μ-CRCR′H) ], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe2(CO)6(μ-CO)(μ-PPh2)]- with CF3COOH and acetylenes. The crystal structure of the complex [Fe2(CO)6(μ-PPh2)(μ-CPHCPhH)] is reported. {\textcopyright} 1990.",

author = "Ram{\'o}n Y{\'a}{\~n}ez and Josep Ros and Ren{\'e} Mathieu and Xavier Solans and Merc{\'e} Font-Bardia",

year = "1990",

month = jun,

day = "12",

doi = "10.1016/0022-328X(90)85413-S",

language = "English",

volume = "389",

pages = "219--226",

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TY - JOUR

T1 - Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe2(CO)6(μ-PPh2(μ-CPhCPhH)]

AU - Yáñez, Ramón

AU - Ros, Josep

AU - Mathieu, René

AU - Solans, Xavier

AU - Font-Bardia, Mercé

PY - 1990/6/12

Y1 - 1990/6/12

N2 - Treatment of [Fe2(CO)6(μ-CO)(μ-CRCR′H)]- (R = R′ = Ph, H an RPh, R′ = Me) with PPh2Cl in CH2Cl2 in the presence of TlBF4 gives complexes of the type [Fe2(CO)6(μ-PPh2)(μ-CRCR′H) ], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe2(CO)6(μ-CO)(μ-PPh2)]- with CF3COOH and acetylenes. The crystal structure of the complex [Fe2(CO)6(μ-PPh2)(μ-CPHCPhH)] is reported. © 1990.

AB - Treatment of [Fe2(CO)6(μ-CO)(μ-CRCR′H)]- (R = R′ = Ph, H an RPh, R′ = Me) with PPh2Cl in CH2Cl2 in the presence of TlBF4 gives complexes of the type [Fe2(CO)6(μ-PPh2)(μ-CRCR′H) ], containing both phosphido and ethenyl bridges. Similar products were isolated from the reaction of [Fe2(CO)6(μ-CO)(μ-PPh2)]- with CF3COOH and acetylenes. The crystal structure of the complex [Fe2(CO)6(μ-PPh2)(μ-CPHCPhH)] is reported. © 1990.

U2 - 10.1016/0022-328X(90)85413-S

DO - 10.1016/0022-328X(90)85413-S

M3 - Article

VL - 389

SP - 219

EP - 226

IS - 2

ER -

Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe2(CO)6(μ-PPh2(μ-CPhCPhH)]

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Synthesis and structure of diiron compounds containing both diphenylphosphido and ethenyl bridges. Crystal structure of [Fe₂(CO)₆(μ-PPh₂(μ-CPhCPhH)]