Synthesis and structure of a chiral dinuclear palladium(0) complex with a 30-membered hexaolefinic macrocyclic ligand

Anna Pla-Quintana, Anna Roglans, Teodor Parella, Jordi Benet-Buchholz

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    2 Citations (Scopus)

    Abstract

    Selective and efficient preparation of a new chiral dipalladium(0) complex with an olefinic macrocyclic ligand named (E,E,E,E,E,E)-1,6,11,16,21,26-hexakis[(4-methylphenyl)sulfonyl]-1,6,11,16,21,26-hexaazacyclotriaconta-3,8,13,18,23,28-hexaenedipalladium(0) (5) is reported. Dinuclear palladium(0) complex 5 has been fully characterized by means of NMR spectroscopy and X-ray diffraction analysis. © 2007 Elsevier B.V. All rights reserved.
    Original languageEnglish
    Pages (from-to)2997-3004
    JournalJournal of Organometallic Chemistry
    Volume692
    Issue number14
    DOIs
    Publication statusPublished - 15 Jun 2007

    Keywords

    • Alkene ligands
    • Dinuclear complexes
    • Macrocycles
    • Palladium
    • Structural elucidation

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