Synthesis and structure of (4R,5R)-α,α,α′,α′-2,2-hexaphenyl-4,5-dimethanol-1,3-dioxolane

J. Irurre, C. Alonso-Alija, J. F. Piniella, A. Alvarez-Larena

Research output: Contribution to journalArticleResearchpeer-review

23 Citations (Scopus)

Abstract

We report the synthesis of the 1,4-diol 2 (4R,5R)-α,α,α′,α′-2,2-hexaphenyl-4,5-dimethanol-1,3-dioxolane from dimethyl-L-tartrate and benzophenone. The X-ray and the IR structural studies on 2 show that this compound has a preferred conformation with OH⋯Ph interactions which are different from related compounds. © 1992.
Original languageEnglish
Pages (from-to)1591-1596
JournalTetrahedron: asymmetry
Volume3
Issue number12
DOIs
Publication statusPublished - 1 Jan 1992

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