Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg<inf>4</inf>(μ<inf>3</inf>, η2-OR)<inf>2</inf> (μ<inf>2</inf>, η2-OR)<inf>4</inf>(OR)<inf>2</inf>] with OR=OCH(CH<inf>3</inf>)CH<inf>2</inf>OCH<inf>3</inf>

Laure Albaric; Nadine Hovnanian; Anne Julbe; Christian Guizard; Angel Alvarez-Larena; Joan F. Piniella

doi:10.1016/0277-5387(96)00327-0

Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg<inf>4</inf>(μ<inf>3</inf>, η2-OR)<inf>2</inf> (μ<inf>2</inf>, η2-OR)<inf>4</inf>(OR)<inf>2</inf>] with OR=OCH(CH<inf>3</inf>)CH<inf>2</inf>OCH<inf>3</inf>

Laure Albaric, Nadine Hovnanian, Anne Julbe, Christian Guizard, Angel Alvarez-Larena, Joan F. Piniella

Department of Geology

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

Direct reaction between magnesium and 1-methoxy-2-propanol yielded the title complex which has been characterized by X-ray crystallography. The molecular structure consists of a centrosymmetric tetrameric unit in which the Mg atoms are five-or six-coordinated by terminal, triple- and double-bridging chelating alkoxo ligands. Copyright © 1996 Elsevier Science Ltd.

Original language	English
Pages (from-to)	587-592
Journal	Polyhedron
Volume	16
Issue number	4
DOIs	https://doi.org/10.1016/0277-5387(96)00327-0
Publication status	Published - 1 Jan 1997

Keywords

Alkoxide
Magnesium
Molecular precursor of oxide material
Sol-gel
X-ray crystallography

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Albaric, L., Hovnanian, N., Julbe, A., Guizard, C., Alvarez-Larena, A., & Piniella, J. F. (1997). Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg<inf>4</inf>(μ<inf>3</inf>, η2-OR)<inf>2</inf> (μ<inf>2</inf>, η2-OR)<inf>4</inf>(OR)<inf>2</inf>] with OR=OCH(CH<inf>3</inf>)CH<inf>2</inf>OCH<inf>3</inf> Polyhedron, 16(4), 587-592. https://doi.org/10.1016/0277-5387(96)00327-0

Albaric, Laure ; Hovnanian, Nadine ; Julbe, Anne ; Guizard, Christian ; Alvarez-Larena, Angel ; Piniella, Joan F. / Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg<inf>4</inf>(μ<inf>3</inf>, η2-OR)<inf>2</inf> (μ<inf>2</inf>, η2-OR)<inf>4</inf>(OR)<inf>2</inf>] with OR=OCH(CH<inf>3</inf>)CH<inf>2</inf>OCH<inf>3</inf>. In: Polyhedron. 1997 ; Vol. 16, No. 4. pp. 587-592.

@article{4f478244a63f413bb70273885710fa03,

title = "Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg4(μ3, η2-OR)2 (μ2, η2-OR)4(OR)2] with OR=OCH(CH3)CH2OCH3",

abstract = "Direct reaction between magnesium and 1-methoxy-2-propanol yielded the title complex which has been characterized by X-ray crystallography. The molecular structure consists of a centrosymmetric tetrameric unit in which the Mg atoms are five-or six-coordinated by terminal, triple- and double-bridging chelating alkoxo ligands. Copyright {\textcopyright} 1996 Elsevier Science Ltd.",

keywords = "Alkoxide, Magnesium, Molecular precursor of oxide material, Sol-gel, X-ray crystallography",

author = "Laure Albaric and Nadine Hovnanian and Anne Julbe and Christian Guizard and Angel Alvarez-Larena and Piniella, {Joan F.}",

year = "1997",

month = jan,

day = "1",

doi = "10.1016/0277-5387(96)00327-0",

language = "English",

volume = "16",

pages = "587--592",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "4",

}

Albaric, L, Hovnanian, N, Julbe, A, Guizard, C, Alvarez-Larena, A & Piniella, JF 1997, 'Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg<inf>4</inf>(μ<inf>3</inf>, η2-OR)<inf>2</inf> (μ<inf>2</inf>, η2-OR)<inf>4</inf>(OR)<inf>2</inf>] with OR=OCH(CH<inf>3</inf>)CH<inf>2</inf>OCH<inf>3</inf>', Polyhedron, vol. 16, no. 4, pp. 587-592. https://doi.org/10.1016/0277-5387(96)00327-0

Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg<inf>4</inf>(μ<inf>3</inf>, η2-OR)<inf>2</inf> (μ<inf>2</inf>, η2-OR)<inf>4</inf>(OR)<inf>2</inf>] with OR=OCH(CH<inf>3</inf>)CH<inf>2</inf>OCH<inf>3</inf> / Albaric, Laure; Hovnanian, Nadine; Julbe, Anne; Guizard, Christian; Alvarez-Larena, Angel; Piniella, Joan F.

In: Polyhedron, Vol. 16, No. 4, 01.01.1997, p. 587-592.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg4(μ3, η2-OR)2 (μ2, η2-OR)4(OR)2] with OR=OCH(CH3)CH2OCH3

AU - Albaric, Laure

AU - Hovnanian, Nadine

AU - Julbe, Anne

AU - Guizard, Christian

AU - Alvarez-Larena, Angel

AU - Piniella, Joan F.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Direct reaction between magnesium and 1-methoxy-2-propanol yielded the title complex which has been characterized by X-ray crystallography. The molecular structure consists of a centrosymmetric tetrameric unit in which the Mg atoms are five-or six-coordinated by terminal, triple- and double-bridging chelating alkoxo ligands. Copyright © 1996 Elsevier Science Ltd.

AB - Direct reaction between magnesium and 1-methoxy-2-propanol yielded the title complex which has been characterized by X-ray crystallography. The molecular structure consists of a centrosymmetric tetrameric unit in which the Mg atoms are five-or six-coordinated by terminal, triple- and double-bridging chelating alkoxo ligands. Copyright © 1996 Elsevier Science Ltd.

KW - Alkoxide

KW - Magnesium

KW - Molecular precursor of oxide material

KW - Sol-gel

KW - X-ray crystallography

U2 - 10.1016/0277-5387(96)00327-0

DO - 10.1016/0277-5387(96)00327-0

M3 - Article

VL - 16

SP - 587

EP - 592

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 4

ER -

Albaric L, Hovnanian N, Julbe A, Guizard C, Alvarez-Larena A, Piniella JF. Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg<inf>4</inf>(μ<inf>3</inf>, η2-OR)<inf>2</inf> (μ<inf>2</inf>, η2-OR)<inf>4</inf>(OR)<inf>2</inf>] with OR=OCH(CH<inf>3</inf>)CH<inf>2</inf>OCH<inf>3</inf> Polyhedron. 1997 Jan 1;16(4):587-592. https://doi.org/10.1016/0277-5387(96)00327-0

Synthesis and structural study of a tetranuclear magnesium alkoxide : [Mg<inf>4</inf>(μ<inf>3</inf>, η<sup>2</sup>-OR)<inf>2</inf> (μ<inf>2</inf>, η<sup>2</sup>-OR)<inf>4</inf>(OR)<inf>2</inf>] with OR=OCH(CH<inf>3</inf>)CH<inf>2</inf>OCH<inf>3</inf>

Abstract

Keywords

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