Synthesis and structural characterization of a dendrimer model compound based on a cyclotriphosphazene core with TEMPO radicals as substituents

Elena Badetti, Vega Lloveras, Klaus Wurst, Rosa María Sebastián, Anne Marie Caminade, Jean Pierre Majoral, Jaume Veciana, José Vidal-Gancedo

Research output: Contribution to journalArticleResearchpeer-review

30 Citations (Scopus)

Abstract

The synthesis of the 3Gc0T zero generation dendrimer with a cyclotriphosphazene core functionalized with nitroxyl radicals in its six branches has been performed. The radical units have been used as probes to determine the orientation of the six branches in solution experimentally by Electron Paramagnetic Resonance (EPR) spectroscopy compared with the structure obtained in the solid state by X-ray diffraction. The orientation of the dendrimer branches is the same in solution as in the solid state. © 2013 American Chemical Society.
Original languageEnglish
Pages (from-to)3490-3493
JournalOrganic Letters
Volume15
Issue number14
DOIs
Publication statusPublished - 19 Jul 2013

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