TY - JOUR
T1 - Synthesis and structural characterisation of a new cobalt(II) pentanuclear complex with a tetranucleating pyrazole-derived ligand
AU - Pons Picart, Josefina
AU - Sanchez, Francisco Javier
AU - Casabó, Jaume
AU - Rius, Jordi
AU - Alvarez-Larena, Angel
AU - Ros, Josep
PY - 2002/2/12
Y1 - 2002/2/12
N2 - Reaction of Co(O2CMe)2·4H2O with HL0 (3,5-bis(6-methyl-2-pyridyl)pyrazole) yielded unexpectedly a new pentanuclear compound Co5(L0)2 (O2CMe)8(H2O)2. The complex has been characterised by elemental analyses, IR and single-crystal X-ray diffraction. The molecular structure is unusual and consists of a centrosymmetrical pentanuclear Co(II) complex containing two 3,5-bis(6-methyl-2-pyridyl)pyrazole ligands, eight MeCOO- anions and two H2O molecules, all co-ordinates. © 2002 Elsevier Science B.V. All rights reserved.
AB - Reaction of Co(O2CMe)2·4H2O with HL0 (3,5-bis(6-methyl-2-pyridyl)pyrazole) yielded unexpectedly a new pentanuclear compound Co5(L0)2 (O2CMe)8(H2O)2. The complex has been characterised by elemental analyses, IR and single-crystal X-ray diffraction. The molecular structure is unusual and consists of a centrosymmetrical pentanuclear Co(II) complex containing two 3,5-bis(6-methyl-2-pyridyl)pyrazole ligands, eight MeCOO- anions and two H2O molecules, all co-ordinates. © 2002 Elsevier Science B.V. All rights reserved.
KW - Cobalt complex
KW - Crystal structure
KW - Pentanuclear complex
KW - Pyrazole complex
U2 - 10.1016/S1387-7003(01)00358-6
DO - 10.1016/S1387-7003(01)00358-6
M3 - Article
VL - 5
SP - 130
EP - 133
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
IS - 2
ER -