Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu2Cl4]2- anion

Lluis Escriche; Natividad Lucena; Jaume Casabó; Francesc Teixidor; Raikko Kivekäs; Reijo Sillanpää

doi:10.1016/0277-5387(94)00289-Q

Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,0^4,5,0^13,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu₂Cl₄]^2- anion

Lluis Escriche, Natividad Lucena, Jaume Casabó, Francesc Teixidor, Raikko Kivekäs, Reijo Sillanpää

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

8 Citations (Scopus)

Abstract

A doubly complex salt containing the atypical non-planar CuI dimeric anion [Cu2Cl4]2- and a CuII containing macrocyclic cation has been synthesized starting from CuCl2·2H2O and a new N2S2 type macrocycle 7,9-diaza-3,14-dithiatetracycle [15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene. The structure of the complex was determined by X-ray crystallography. © 1995.

Original language	English
Pages (from-to)	649-654
Journal	Polyhedron
Volume	14
Issue number	5
DOIs	https://doi.org/10.1016/0277-5387(94)00289-Q
Publication status	Published - 1 Jan 1995

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Escriche, L., Lucena, N., Casabó, J., Teixidor, F., Kivekäs, R., & Sillanpää, R. (1995). Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,0^4,5,0^13,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu₂Cl₄]^2- anion. Polyhedron, 14(5), 649-654. https://doi.org/10.1016/0277-5387(94)00289-Q

Escriche, Lluis ; Lucena, Natividad ; Casabó, Jaume ; Teixidor, Francesc ; Kivekäs, Raikko ; Sillanpää, Reijo. / Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,0^4,5,0^13,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu₂Cl₄]^2- anion. In: Polyhedron. 1995 ; Vol. 14, No. 5. pp. 649-654.

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title = "Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu2Cl4]2- anion",

abstract = "A doubly complex salt containing the atypical non-planar CuI dimeric anion [Cu2Cl4]2- and a CuII containing macrocyclic cation has been synthesized starting from CuCl2·2H2O and a new N2S2 type macrocycle 7,9-diaza-3,14-dithiatetracycle [15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene. The structure of the complex was determined by X-ray crystallography. {\textcopyright} 1995.",

author = "Lluis Escriche and Natividad Lucena and Jaume Casab{\'o} and Francesc Teixidor and Raikko Kivek{\"a}s and Reijo Sillanp{\"a}{\"a}",

year = "1995",

month = jan,

day = "1",

doi = "10.1016/0277-5387(94)00289-Q",

language = "English",

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pages = "649--654",

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Escriche, L, Lucena, N, Casabó, J, Teixidor, F, Kivekäs, R & Sillanpää, R 1995, 'Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,0^4,5,0^13,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu₂Cl₄]^2- anion', Polyhedron, vol. 14, no. 5, pp. 649-654. https://doi.org/10.1016/0277-5387(94)00289-Q

Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,0^4,5,0^13,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu₂Cl₄]^2- anion. / Escriche, Lluis; Lucena, Natividad; Casabó, Jaume; Teixidor, Francesc; Kivekäs, Raikko; Sillanpää, Reijo.

In: Polyhedron, Vol. 14, No. 5, 01.01.1995, p. 649-654.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu2Cl4]2- anion

AU - Escriche, Lluis

AU - Lucena, Natividad

AU - Casabó, Jaume

AU - Teixidor, Francesc

AU - Kivekäs, Raikko

AU - Sillanpää, Reijo

PY - 1995/1/1

Y1 - 1995/1/1

N2 - A doubly complex salt containing the atypical non-planar CuI dimeric anion [Cu2Cl4]2- and a CuII containing macrocyclic cation has been synthesized starting from CuCl2·2H2O and a new N2S2 type macrocycle 7,9-diaza-3,14-dithiatetracycle [15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene. The structure of the complex was determined by X-ray crystallography. © 1995.

AB - A doubly complex salt containing the atypical non-planar CuI dimeric anion [Cu2Cl4]2- and a CuII containing macrocyclic cation has been synthesized starting from CuCl2·2H2O and a new N2S2 type macrocycle 7,9-diaza-3,14-dithiatetracycle [15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene. The structure of the complex was determined by X-ray crystallography. © 1995.

U2 - 10.1016/0277-5387(94)00289-Q

DO - 10.1016/0277-5387(94)00289-Q

M3 - Article

VL - 14

SP - 649

EP - 654

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 5

ER -

Escriche L, Lucena N, Casabó J, Teixidor F, Kivekäs R, Sillanpää R. Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,0^4,5,0^13,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu₂Cl₄]^2- anion. Polyhedron. 1995 Jan 1;14(5):649-654. https://doi.org/10.1016/0277-5387(94)00289-Q