Synthesis and crystal structure of bis[(7,9-diaza-3,14-dithiatetracycle[15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene)chlorocopper(II)] tetrachlorodicuprate(I) bismethanol. Atypical non-planar conformation of the [Cu2Cl4]2- anion

Lluis Escriche, Natividad Lucena, Jaume Casabó, Francesc Teixidor, Raikko Kivekäs, Reijo Sillanpää

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Abstract

A doubly complex salt containing the atypical non-planar CuI dimeric anion [Cu2Cl4]2- and a CuII containing macrocyclic cation has been synthesized starting from CuCl2·2H2O and a new N2S2 type macrocycle 7,9-diaza-3,14-dithiatetracycle [15,4,0,04,5,013,14]nonacosa-1(17),18,20,4(22),23,25,13(26),27,29-nonaene. The structure of the complex was determined by X-ray crystallography. © 1995.
Original languageEnglish
Pages (from-to)649-654
JournalPolyhedron
Volume14
Issue number5
DOIs
Publication statusPublished - 1 Jan 1995

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