Synthesis and crystal structure of μ-chloro-μ-(diphenylethenyl)hexacarbonyldiiron(FeFe)

Josep Ros, Josep M. Viñas, René Mathieu, Xavier Solans, Mercè Font-Bardia

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12 Citations (Scopus)

Abstract

Treatment of PPh4[Fe2(CO)6(μ-CO)(μ-C(Ph)C(Ph)H)] with Me3OSbCl6 gives the chloro-bridged derivative [Fe2(CO)6(μ-Cl)(μ-C(Ph)C(Ph)H)]. The structure of this compound has been established by X-ray diffraction. The title complex appears to be formed by successive methylation of bridging carbon monoxide and replacement of the methoxycarbyne by the chloride ligand. © 1986.
Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume307
Issue number1
DOIs
Publication statusPublished - 10 Jun 1986

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