Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs

Henri Arzoumanian; Giuseppe Agrifoglio; Mario V. Capparelli; Reinaldo Atencio; Alexander Briceño; Angel Alvarez-Larena

doi:10.1016/j.ica.2005.08.003

Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs

Henri Arzoumanian, Giuseppe Agrifoglio, Mario V. Capparelli, Reinaldo Atencio, Alexander Briceño, Angel Alvarez-Larena

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. © 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	81-89
Journal	Inorganica Chimica Acta
Volume	359
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2005.08.003
Publication status	Published - 1 Jan 2006

Keywords

Oxygen atom transfer
Tungsten oxo complexes
X-ray structures

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10.1016/j.ica.2005.08.003

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title = "Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs",

abstract = "Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. {\textcopyright} 2005 Elsevier B.V. All rights reserved.",

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author = "Henri Arzoumanian and Giuseppe Agrifoglio and Capparelli, {Mario V.} and Reinaldo Atencio and Alexander Brice{\~n}o and Angel Alvarez-Larena",

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Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs. / Arzoumanian, Henri; Agrifoglio, Giuseppe; Capparelli, Mario V.; Atencio, Reinaldo; Briceño, Alexander; Alvarez-Larena, Angel.

In: Inorganica Chimica Acta, Vol. 359, No. 1, 01.01.2006, p. 81-89.

Research output: Contribution to journal › Article › Research › peer-review

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T1 - Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs

AU - Arzoumanian, Henri

AU - Agrifoglio, Giuseppe

AU - Capparelli, Mario V.

AU - Atencio, Reinaldo

AU - Briceño, Alexander

AU - Alvarez-Larena, Angel

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N2 - Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. © 2005 Elsevier B.V. All rights reserved.

AB - Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. © 2005 Elsevier B.V. All rights reserved.

KW - Oxygen atom transfer

KW - Tungsten oxo complexes

KW - X-ray structures

U2 - 10.1016/j.ica.2005.08.003

DO - 10.1016/j.ica.2005.08.003

M3 - Article

VL - 359

SP - 81

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