Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs

Henri Arzoumanian, Giuseppe Agrifoglio, Mario V. Capparelli, Reinaldo Atencio, Alexander Briceño, Angel Alvarez-Larena

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    Abstract

    Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. © 2005 Elsevier B.V. All rights reserved.
    Original languageEnglish
    Pages (from-to)81-89
    JournalInorganica Chimica Acta
    Volume359
    Issue number1
    DOIs
    Publication statusPublished - 1 Jan 2006

    Keywords

    • Oxygen atom transfer
    • Tungsten oxo complexes
    • X-ray structures

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    Arzoumanian, H., Agrifoglio, G., Capparelli, M. V., Atencio, R., Briceño, A., & Alvarez-Larena, A. (2006). Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs. Inorganica Chimica Acta, 359(1), 81-89. https://doi.org/10.1016/j.ica.2005.08.003