Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs

Henri Arzoumanian; Giuseppe Agrifoglio; Mario V. Capparelli; Reinaldo Atencio; Alexander Briceño; Angel Alvarez-Larena

doi:10.1016/j.ica.2005.08.003

Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs

Henri Arzoumanian, Giuseppe Agrifoglio, Mario V. Capparelli, Reinaldo Atencio, Alexander Briceño, Angel Alvarez-Larena

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. © 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	81-89
Journal	Inorganica Chimica Acta
Volume	359
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2005.08.003
Publication status	Published - 1 Jan 2006

Keywords

Oxygen atom transfer
Tungsten oxo complexes
X-ray structures

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Arzoumanian, H., Agrifoglio, G., Capparelli, M. V., Atencio, R., Briceño, A., & Alvarez-Larena, A. (2006). Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs. Inorganica Chimica Acta, 359(1), 81-89. https://doi.org/10.1016/j.ica.2005.08.003

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Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs. / Arzoumanian, Henri; Agrifoglio, Giuseppe; Capparelli, Mario V.; Atencio, Reinaldo; Briceño, Alexander; Alvarez-Larena, Angel.

In: Inorganica Chimica Acta, Vol. 359, No. 1, 01.01.2006, p. 81-89.

Research output: Contribution to journal › Article › Research › peer-review

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AU - Atencio, Reinaldo

AU - Briceño, Alexander

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KW - Tungsten oxo complexes

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