TY - JOUR
T1 - Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs
AU - Arzoumanian, Henri
AU - Agrifoglio, Giuseppe
AU - Capparelli, Mario V.
AU - Atencio, Reinaldo
AU - Briceño, Alexander
AU - Alvarez-Larena, Angel
PY - 2006/1/1
Y1 - 2006/1/1
N2 - Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. © 2005 Elsevier B.V. All rights reserved.
AB - Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. © 2005 Elsevier B.V. All rights reserved.
KW - Oxygen atom transfer
KW - Tungsten oxo complexes
KW - X-ray structures
U2 - 10.1016/j.ica.2005.08.003
DO - 10.1016/j.ica.2005.08.003
M3 - Article
VL - 359
SP - 81
EP - 89
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
SN - 0020-1693
IS - 1
ER -