Four new tungsten-oxo(VI) complexes have been synthesized, characterized spectroscopically and their molecular structure established by X-ray diffraction analysis. These bear identical environment as previously reported molybdenum-oxo(VI) complexes, which allowed direct comparison of their spectroscopic properties. Their capability as oxygen atom transfer agents was found to be significantly lower than their molybdenum analogs. © 2005 Elsevier B.V. All rights reserved.
|Journal||Inorganica Chimica Acta|
|Publication status||Published - 1 Jan 2006|
- Oxygen atom transfer
- Tungsten oxo complexes
- X-ray structures
Arzoumanian, H., Agrifoglio, G., Capparelli, M. V., Atencio, R., Briceño, A., & Alvarez-Larena, A. (2006). Synthesis and characterization of thiocyanato and chlorodioxo tungsten(VI) compounds: Comparative oxygen atom transfer capability with molybdenum analogs. Inorganica Chimica Acta, 359(1), 81-89. https://doi.org/10.1016/j.ica.2005.08.003