Synthesis and characterization of endohedral metallofulleride K(18-crown-6)[Ho@C<inf>82</inf>(C <inf>2v</inf>)]

V. M. Nekrasov; V. P. Bubnov; V. M. Martynenko; I. E. Kareev; E. Laukhina; J. Veciana; C. Rovira

doi:10.1007/s11172-015-1179-9

Synthesis and characterization of endohedral metallofulleride K(18-crown-6)[Ho@C<inf>82</inf>(C <inf>2v</inf>)]

V. M. Nekrasov, V. P. Bubnov, V. M. Martynenko, I. E. Kareev, E. Laukhina, J. Veciana, C. Rovira

Research output: Contribution to journal › Article › Research › peer-review

4 Citations (Scopus)

Abstract

© 2015, Springer Science+Business Media New York. Endohedral metallofulleride K(18-crown-6)[Ho@C82(C2v)] was synthesized for the first time using a redox reaction of endohedral metallofullerene Ho@C82(C2v) with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The new salt was characterized by spectrophotometry and mass spectrometry.

Original language	English
Pages (from-to)	2473-2476
Journal	Russian Chemical Bulletin
Volume	64
Issue number	10
DOIs	https://doi.org/10.1007/s11172-015-1179-9
Publication status	Published - 1 Oct 2015

Keywords

arc synthesis
donor-acceptor systems
electron transfer
endohedral metallofullerenes
HPLC
mass spectrometry
optical spectroscopy

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10.1007/s11172-015-1179-9

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title = "Synthesis and characterization of endohedral metallofulleride K(18-crown-6)[Ho@C82(C 2v)]",

abstract = "{\textcopyright} 2015, Springer Science+Business Media New York. Endohedral metallofulleride K(18-crown-6)[Ho@C82(C2v)] was synthesized for the first time using a redox reaction of endohedral metallofullerene Ho@C82(C2v) with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The new salt was characterized by spectrophotometry and mass spectrometry.",

keywords = "arc synthesis, donor-acceptor systems, electron transfer, endohedral metallofullerenes, HPLC, mass spectrometry, optical spectroscopy",

author = "Nekrasov, {V. M.} and Bubnov, {V. P.} and Martynenko, {V. M.} and Kareev, {I. E.} and E. Laukhina and J. Veciana and C. Rovira",

year = "2015",

month = oct,

day = "1",

doi = "10.1007/s11172-015-1179-9",

language = "English",

volume = "64",

pages = "2473--2476",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "10",

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TY - JOUR

T1 - Synthesis and characterization of endohedral metallofulleride K(18-crown-6)[Ho@C82(C 2v)]

AU - Nekrasov, V. M.

AU - Bubnov, V. P.

AU - Martynenko, V. M.

AU - Kareev, I. E.

AU - Laukhina, E.

AU - Veciana, J.

AU - Rovira, C.

PY - 2015/10/1

Y1 - 2015/10/1

N2 - © 2015, Springer Science+Business Media New York. Endohedral metallofulleride K(18-crown-6)[Ho@C82(C2v)] was synthesized for the first time using a redox reaction of endohedral metallofullerene Ho@C82(C2v) with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The new salt was characterized by spectrophotometry and mass spectrometry.

AB - © 2015, Springer Science+Business Media New York. Endohedral metallofulleride K(18-crown-6)[Ho@C82(C2v)] was synthesized for the first time using a redox reaction of endohedral metallofullerene Ho@C82(C2v) with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The new salt was characterized by spectrophotometry and mass spectrometry.

KW - arc synthesis

KW - donor-acceptor systems

KW - electron transfer

KW - endohedral metallofullerenes

KW - HPLC

KW - mass spectrometry

KW - optical spectroscopy

U2 - 10.1007/s11172-015-1179-9

DO - 10.1007/s11172-015-1179-9

M3 - Article

SN - 1066-5285

VL - 64

SP - 2473

EP - 2476

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 10

ER -

Synthesis and characterization of endohedral metallofulleride K(18-crown-6)[Ho@C<inf>82</inf>(C <inf>2v</inf>)]

Abstract

Keywords

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