Synthesis and characterization of endohedral metallofulleride K(18-crown-6)[Ho@C<inf>82</inf>(C <inf>2v</inf>)]

V. M. Nekrasov, V. P. Bubnov, V. M. Martynenko, I. E. Kareev, E. Laukhina, J. Veciana, C. Rovira

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    4 Citations (Scopus)

    Abstract

    © 2015, Springer Science+Business Media New York. Endohedral metallofulleride K(18-crown-6)[Ho@C82(C2v)] was synthesized for the first time using a redox reaction of endohedral metallofullerene Ho@C82(C2v) with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The new salt was characterized by spectrophotometry and mass spectrometry.
    Original languageEnglish
    Pages (from-to)2473-2476
    JournalRussian Chemical Bulletin
    Volume64
    Issue number10
    DOIs
    Publication statusPublished - 1 Oct 2015

    Keywords

    • arc synthesis
    • donor-acceptor systems
    • electron transfer
    • endohedral metallofullerenes
    • HPLC
    • mass spectrometry
    • optical spectroscopy

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