Synthesis and characterization of 1-Methyl-4-mercaptopiperidine complexes of nickel(II), palladium(II) and platinum(II)

Rosa María Brunet, Walter Gaete, Pilar González-Duarte, Josep Ros

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Abstract

Complexes of formulae Ni(HRS)2X2 (X=Cl or Br), M(HRS)2Y2 (M=Ni or Pd; Y=NO2 or C1O4), Pd(HRS)X2 (X=Cl, Br or I), Pt(HRS)X2 (X=Cl or Br), Pt(HRS)2(ClO4)2 and M(RS)2 (M=Pd or Pt) where HRS and RS denote 1-methyl-4-mercaptopiperidine in the zwitterionic or in the thiolato form, respectively, have been prepared and characterized. In all the complexes the ligands are coordinated exclusively through sulphur. Polymeric structures consisting of square-planar geometry with sulphur-bridged metal atoms are proposed in each case. © 1984 Verlag Chemie GmbH.
Original languageEnglish
Pages (from-to)345-347
JournalTransition Metal Chemistry
Volume9
Issue number9
DOIs
Publication statusPublished - 1 Sep 1984

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