Complexes of formulae Ni(HRS)2X2 (X=Cl or Br), M(HRS)2Y2 (M=Ni or Pd; Y=NO2 or C1O4), Pd(HRS)X2 (X=Cl, Br or I), Pt(HRS)X2 (X=Cl or Br), Pt(HRS)2(ClO4)2 and M(RS)2 (M=Pd or Pt) where HRS and RS denote 1-methyl-4-mercaptopiperidine in the zwitterionic or in the thiolato form, respectively, have been prepared and characterized. In all the complexes the ligands are coordinated exclusively through sulphur. Polymeric structures consisting of square-planar geometry with sulphur-bridged metal atoms are proposed in each case. © 1984 Verlag Chemie GmbH.
|Journal||Transition Metal Chemistry|
|Publication status||Published - 1 Sep 1984|