Synergistic Effect of Tartaric Acid in the Extraction of Iron(III) from Aqueous Nitrate by Di(2-ethyl hexyl)phosphoric Acid in Hexane

Victoria Salvadó; Amalia Masana; Mamoun Muhammed; Maria Muñoz; Manuel Valiente

doi:10.2116/analsci.6.867

Synergistic Effect of Tartaric Acid in the Extraction of Iron(III) from Aqueous Nitrate by Di(2-ethyl hexyl)phosphoric Acid in Hexane

Victoria Salvadó, Amalia Masana, Mamoun Muhammed, Maria Muñoz, Manuel Valiente

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

2 Citations (Scopus)

Abstract

The addition of tartaric acid to aqueous nitrate solutions containing Fe(III) produces an increase in the solvent extraction of Fe(III) by di(2-ethyl hexyl)phosphoric acid, DEHPA, in hexane solutions. This effect has been studied and it is explained in terms of chemical equilibrium between the two liquid phases by applying the following reactions: [formula omitted]; eq. const. logβ=7.18±0.03 and [formula omitted]. Here, HA stands for DEHPA and L represents tartaric acid. Such behavior determines the formation of a FeLA(HA) metal complex species of mixed ligand composition in the organic phase. © 1990, The Japan Society for Analytical Chemistry. All rights reserved.

Original language	English
Pages (from-to)	867-870
Journal	Analytical Sciences
Volume	6
Issue number	6
DOIs	https://doi.org/10.2116/analsci.6.867
Publication status	Published - 1 Jan 1990

Keywords

di(2-ethyl hexyl)phosphoric acid
Iron(III)
radiotracer determination
solvent extraction
synergistic effect
tartaric acid

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10.2116/analsci.6.867

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title = "Synergistic Effect of Tartaric Acid in the Extraction of Iron(III) from Aqueous Nitrate by Di(2-ethyl hexyl)phosphoric Acid in Hexane",

abstract = "The addition of tartaric acid to aqueous nitrate solutions containing Fe(III) produces an increase in the solvent extraction of Fe(III) by di(2-ethyl hexyl)phosphoric acid, DEHPA, in hexane solutions. This effect has been studied and it is explained in terms of chemical equilibrium between the two liquid phases by applying the following reactions: [formula omitted]; eq. const. logβ=7.18±0.03 and [formula omitted]. Here, HA stands for DEHPA and L represents tartaric acid. Such behavior determines the formation of a FeLA(HA) metal complex species of mixed ligand composition in the organic phase. {\textcopyright} 1990, The Japan Society for Analytical Chemistry. All rights reserved.",

keywords = "di(2-ethyl hexyl)phosphoric acid, Iron(III), radiotracer determination, solvent extraction, synergistic effect, tartaric acid",

author = "Victoria Salvad{\'o} and Amalia Masana and Mamoun Muhammed and Maria Mu{\~n}oz and Manuel Valiente",

year = "1990",

month = jan,

day = "1",

doi = "10.2116/analsci.6.867",

language = "English",

volume = "6",

pages = "867--870",

journal = "Analytical Sciences",

issn = "0910-6340",

number = "6",

}

TY - JOUR

T1 - Synergistic Effect of Tartaric Acid in the Extraction of Iron(III) from Aqueous Nitrate by Di(2-ethyl hexyl)phosphoric Acid in Hexane

AU - Salvadó, Victoria

AU - Masana, Amalia

AU - Muhammed, Mamoun

AU - Muñoz, Maria

AU - Valiente, Manuel

PY - 1990/1/1

Y1 - 1990/1/1

N2 - The addition of tartaric acid to aqueous nitrate solutions containing Fe(III) produces an increase in the solvent extraction of Fe(III) by di(2-ethyl hexyl)phosphoric acid, DEHPA, in hexane solutions. This effect has been studied and it is explained in terms of chemical equilibrium between the two liquid phases by applying the following reactions: [formula omitted]; eq. const. logβ=7.18±0.03 and [formula omitted]. Here, HA stands for DEHPA and L represents tartaric acid. Such behavior determines the formation of a FeLA(HA) metal complex species of mixed ligand composition in the organic phase. © 1990, The Japan Society for Analytical Chemistry. All rights reserved.

AB - The addition of tartaric acid to aqueous nitrate solutions containing Fe(III) produces an increase in the solvent extraction of Fe(III) by di(2-ethyl hexyl)phosphoric acid, DEHPA, in hexane solutions. This effect has been studied and it is explained in terms of chemical equilibrium between the two liquid phases by applying the following reactions: [formula omitted]; eq. const. logβ=7.18±0.03 and [formula omitted]. Here, HA stands for DEHPA and L represents tartaric acid. Such behavior determines the formation of a FeLA(HA) metal complex species of mixed ligand composition in the organic phase. © 1990, The Japan Society for Analytical Chemistry. All rights reserved.

KW - di(2-ethyl hexyl)phosphoric acid

KW - Iron(III)

KW - radiotracer determination

KW - solvent extraction

KW - synergistic effect

KW - tartaric acid

U2 - 10.2116/analsci.6.867

DO - 10.2116/analsci.6.867

M3 - Article

SN - 0910-6340

VL - 6

SP - 867

EP - 870

JO - Analytical Sciences

JF - Analytical Sciences

IS - 6

ER -

Synergistic Effect of Tartaric Acid in the Extraction of Iron(III) from Aqueous Nitrate by Di(2-ethyl hexyl)phosphoric Acid in Hexane

Abstract

Keywords

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