Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

Marcial Moreno-Mañas; Roser Pleixats; Anna Serra-Muns

doi:10.1055/s-2006-948173

Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

Marcial Moreno-Mañas, Roser Pleixats, Anna Serra-Muns

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

29 Citations (Scopus)

Abstract

The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex. © Georg Thieme Verlag Stuttgart.

Original language	English
Pages (from-to)	3001-3004
Journal	Synlett
Issue number	18
DOIs	https://doi.org/10.1055/s-2006-948173
Publication status	Published - 3 Nov 2006

Keywords

Catalysis by palladium
Macrocycle
Olefin complex
Recovery

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title = "Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst",

abstract = "The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex. {\textcopyright} Georg Thieme Verlag Stuttgart.",

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author = "Marcial Moreno-Ma{\~n}as and Roser Pleixats and Anna Serra-Muns",

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doi = "10.1055/s-2006-948173",

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T1 - Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

AU - Moreno-Mañas, Marcial

AU - Pleixats, Roser

AU - Serra-Muns, Anna

PY - 2006/11/3

Y1 - 2006/11/3

N2 - The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex. © Georg Thieme Verlag Stuttgart.

AB - The combination of a bulky aliphatic phosphine, e.g. tricyclohexylphosphine or the tetrafluoroborate salt of tri-tert-butylphosphine, with the Pd(0) complex of a 15-membered triolefinic macrocycle is an excellent catalyst for the Suzuki cross-coupling of aryl and heteroaryl bromides and chlorides. The palladium can be recovered in the form of the initial complex. © Georg Thieme Verlag Stuttgart.

KW - Catalysis by palladium

KW - Macrocycle

KW - Olefin complex

KW - Recovery

U2 - 10.1055/s-2006-948173

DO - 10.1055/s-2006-948173

M3 - Article

SN - 0936-5214

SP - 3001

EP - 3004

JO - Synlett

JF - Synlett

IS - 18

ER -

Suzuki cross-couplings on aryl (heteroaryl) bromides and chlorides with bulky aliphatic phosphines/Pd(0)-triolefinic macrocyclic catalyst

Abstract

Keywords

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