Study of the reactivity of [Fe2(CO)6(.mu.-CO)(.mu.-CPhCPhH)]- toward the MeOC(O)C.tplbond.CC(O)OMe and CF3C.tplbond.CCF3 alkynes. Crystal structure of the products resulting from two different modes of combination of the alkynes with the bridging ligands [Fe2(CO)6(.mu.-C(C(O)OMe)C(C(O)OMe)C(O)CPhCPhH)]- and [Fe2(CO)6(.mu.-CPhCPhC(CF3)C(CF3)H)]

Josep Ros, Xavier Solans, Manuel Font-Altaba, René Mathieu

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Dive into the research topics of 'Study of the reactivity of [Fe2(CO)6(.mu.-CO)(.mu.-CPhCPhH)]- toward the MeOC(O)C.tplbond.CC(O)OMe and CF3C.tplbond.CCF3 alkynes. Crystal structure of the products resulting from two different modes of combination of the alkynes with the bridging ligands [Fe2(CO)6(.mu.-C(C(O)OMe)C(C(O)OMe)C(O)CPhCPhH)]- and [Fe2(CO)6(.mu.-CPhCPhC(CF3)C(CF3)H)]'. Together they form a unique fingerprint.

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Chemistry