Study of the coordination behaviour of (3,5-diphenyl-1H-pyrazol-1-yl) ethanol against Pd(II), Zn(II) and Cu(II)

Sergio Muñoz; Josefina Pons; Josep Ros; Mercè Font-Bardia; Colin A. Kilner; Malcolm A. Halcrow

doi:https://doi.org/10.1016/j.ica.2011.04.027

Study of the coordination behaviour of (3,5-diphenyl-1H-pyrazol-1-yl) ethanol against Pd(II), Zn(II) and Cu(II)

Sergio Muñoz, Josefina Pons, Josep Ros, Mercè Font-Bardia, Colin A. Kilner, Malcolm A. Halcrow

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

12 Citations (Scopus)

Abstract

A new easily synthetic route with a 96% yield of ligand 2-(3,5-diphenyl-1H-pyrazol-1-yl)ethanol (L) is obtained. The reactivity of L against Pd(II), Zn(II) and Cu(II) leads to [PdCl2(L)2] (1), [ZnCl2(L)] (2) and [CuCl(L′)]2 (3) (L′ is the ligand L without alcoholic proton), respectively. According to the different geometries imposed by the metallic centre and the capability of L to present various coordination links, it has been obtained complexes with square planar (1 and 3) or tetrahedral (2) geometry and different nuclearity: monomeric (1 and 2) or dimeric (3). Complete characterisation by analytical and spectroscopic methods, resolution of L and 1-3 by single-crystal X-ray diffraction and magnetic studies for complex 3 are presented. © 2011 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	211-218
Journal	Inorganica Chimica Acta
Volume	373
DOIs	https://doi.org/10.1016/j.ica.2011.04.027
Publication status	Published - 15 Jul 2011

Keywords

Copper(II)
Hybrid N,O ligand
Magnetic properties
Palladium(II)
X-ray structures
Zinc(II)

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@article{19a97dd6ed1045e6b193336c526ccf4e,

title = "Study of the coordination behaviour of (3,5-diphenyl-1H-pyrazol-1-yl) ethanol against Pd(II), Zn(II) and Cu(II)",

abstract = "A new easily synthetic route with a 96% yield of ligand 2-(3,5-diphenyl-1H-pyrazol-1-yl)ethanol (L) is obtained. The reactivity of L against Pd(II), Zn(II) and Cu(II) leads to [PdCl2(L)2] (1), [ZnCl2(L)] (2) and [CuCl(L′)]2 (3) (L′ is the ligand L without alcoholic proton), respectively. According to the different geometries imposed by the metallic centre and the capability of L to present various coordination links, it has been obtained complexes with square planar (1 and 3) or tetrahedral (2) geometry and different nuclearity: monomeric (1 and 2) or dimeric (3). Complete characterisation by analytical and spectroscopic methods, resolution of L and 1-3 by single-crystal X-ray diffraction and magnetic studies for complex 3 are presented. {\textcopyright} 2011 Elsevier B.V. All rights reserved.",

keywords = "Copper(II), Hybrid N,O ligand, Magnetic properties, Palladium(II), X-ray structures, Zinc(II)",

author = "Sergio Mu{\~n}oz and Josefina Pons and Josep Ros and Merc{\`e} Font-Bardia and Kilner, {Colin A.} and Halcrow, {Malcolm A.}",

year = "2011",

month = jul,

day = "15",

doi = "https://doi.org/10.1016/j.ica.2011.04.027",

language = "English",

volume = "373",

pages = "211--218",

journal = "Inorganica Chimica Acta",

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T1 - Study of the coordination behaviour of (3,5-diphenyl-1H-pyrazol-1-yl) ethanol against Pd(II), Zn(II) and Cu(II)

AU - Muñoz, Sergio

AU - Pons, Josefina

AU - Ros, Josep

AU - Font-Bardia, Mercè

AU - Kilner, Colin A.

AU - Halcrow, Malcolm A.

PY - 2011/7/15

Y1 - 2011/7/15

N2 - A new easily synthetic route with a 96% yield of ligand 2-(3,5-diphenyl-1H-pyrazol-1-yl)ethanol (L) is obtained. The reactivity of L against Pd(II), Zn(II) and Cu(II) leads to [PdCl2(L)2] (1), [ZnCl2(L)] (2) and [CuCl(L′)]2 (3) (L′ is the ligand L without alcoholic proton), respectively. According to the different geometries imposed by the metallic centre and the capability of L to present various coordination links, it has been obtained complexes with square planar (1 and 3) or tetrahedral (2) geometry and different nuclearity: monomeric (1 and 2) or dimeric (3). Complete characterisation by analytical and spectroscopic methods, resolution of L and 1-3 by single-crystal X-ray diffraction and magnetic studies for complex 3 are presented. © 2011 Elsevier B.V. All rights reserved.

AB - A new easily synthetic route with a 96% yield of ligand 2-(3,5-diphenyl-1H-pyrazol-1-yl)ethanol (L) is obtained. The reactivity of L against Pd(II), Zn(II) and Cu(II) leads to [PdCl2(L)2] (1), [ZnCl2(L)] (2) and [CuCl(L′)]2 (3) (L′ is the ligand L without alcoholic proton), respectively. According to the different geometries imposed by the metallic centre and the capability of L to present various coordination links, it has been obtained complexes with square planar (1 and 3) or tetrahedral (2) geometry and different nuclearity: monomeric (1 and 2) or dimeric (3). Complete characterisation by analytical and spectroscopic methods, resolution of L and 1-3 by single-crystal X-ray diffraction and magnetic studies for complex 3 are presented. © 2011 Elsevier B.V. All rights reserved.

KW - Copper(II)

KW - Hybrid N,O ligand

KW - Magnetic properties

KW - Palladium(II)

KW - X-ray structures

KW - Zinc(II)

U2 - https://doi.org/10.1016/j.ica.2011.04.027

DO - https://doi.org/10.1016/j.ica.2011.04.027

M3 - Article

SN - 0020-1693

VL - 373

SP - 211

EP - 218

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Study of the coordination behaviour of (3,5-diphenyl-1H-pyrazol-1-yl) ethanol against Pd(II), Zn(II) and Cu(II)

Abstract

Keywords

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