Structural study of electrochemically-synthesized Ag<inf>2</inf>Cu<inf>2</inf>O<inf>4</inf>. A novel oxide sensitive to irradiation

D. Munoz-Rojas; J. Fraxedas; J. Oró; P. Gómez-Romero; N. Casañ-Pastor

doi:10.1016/S1463-0184(02)00057-6

Structural study of electrochemically-synthesized Ag<inf>2</inf>Cu<inf>2</inf>O<inf>4</inf>. A novel oxide sensitive to irradiation

D. Munoz-Rojas, J. Fraxedas, J. Oró, P. Gómez-Romero, N. Casañ-Pastor

Research output: Contribution to journal › Article › Research › peer-review

23 Citations (Scopus)

Abstract

The structure of Ag2Cu2O4 synthesized by electrochemical oxidation of its precursor Ag2Cu2O3 is studied under a new perspective. Irradiation of the oxide with X-ray beam transforms the electronic structure of the phase by redistributing the internal charge within the material. The refined structure shows several possibilities all with metals in the same arrangement, but with oxygen atoms distributed in a rather disordered way. This is typical of ionic conductors. © 2003 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	459-467
Journal	Crystal Engineering
Volume	5
Issue number	3-4
DOIs	https://doi.org/10.1016/S1463-0184(02)00057-6
Publication status	Published - 1 Jan 2002

Keywords

Ag2Cu2O4
AgCuO2
Electrochemical
Silver copper oxides
Solid state
Structural refinement

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10.1016/S1463-0184(02)00057-6

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title = "Structural study of electrochemically-synthesized Ag2Cu2O4. A novel oxide sensitive to irradiation",

abstract = "The structure of Ag2Cu2O4 synthesized by electrochemical oxidation of its precursor Ag2Cu2O3 is studied under a new perspective. Irradiation of the oxide with X-ray beam transforms the electronic structure of the phase by redistributing the internal charge within the material. The refined structure shows several possibilities all with metals in the same arrangement, but with oxygen atoms distributed in a rather disordered way. This is typical of ionic conductors. {\textcopyright} 2003 Elsevier Science Ltd. All rights reserved.",

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author = "D. Munoz-Rojas and J. Fraxedas and J. Or{\'o} and P. G{\'o}mez-Romero and N. Casa{\~n}-Pastor",

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AU - Munoz-Rojas, D.

AU - Fraxedas, J.

AU - Oró, J.

AU - Gómez-Romero, P.

AU - Casañ-Pastor, N.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - The structure of Ag2Cu2O4 synthesized by electrochemical oxidation of its precursor Ag2Cu2O3 is studied under a new perspective. Irradiation of the oxide with X-ray beam transforms the electronic structure of the phase by redistributing the internal charge within the material. The refined structure shows several possibilities all with metals in the same arrangement, but with oxygen atoms distributed in a rather disordered way. This is typical of ionic conductors. © 2003 Elsevier Science Ltd. All rights reserved.

AB - The structure of Ag2Cu2O4 synthesized by electrochemical oxidation of its precursor Ag2Cu2O3 is studied under a new perspective. Irradiation of the oxide with X-ray beam transforms the electronic structure of the phase by redistributing the internal charge within the material. The refined structure shows several possibilities all with metals in the same arrangement, but with oxygen atoms distributed in a rather disordered way. This is typical of ionic conductors. © 2003 Elsevier Science Ltd. All rights reserved.

KW - Ag2Cu2O4

KW - AgCuO2

KW - Electrochemical

KW - Silver copper oxides

KW - Solid state

KW - Structural refinement

U2 - 10.1016/S1463-0184(02)00057-6

DO - 10.1016/S1463-0184(02)00057-6

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VL - 5

SP - 459

EP - 467

IS - 3-4

ER -