Structural analysis of chiral complexes of pallad him (0) with 15-membered triolefinic macrocyclic ligands

Anna Pla-Quintana, Anna Roglans, J. Vicente De Julián-Ortiz, Marcial Moreno-Mañas, Teodor Parella, Jordi Benet-Buchholz, Xavier Solans

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14 Citations (Scopus)

Abstract

The complete structural analysis of the palladium complexes of the triolefinic macrocycles (E,E,E)-1,6,11-tris(arylsulfonyl)-1,6,11- triazacyclopentadeca-3,8,13-trienes, which featured from three identical to three different aryl groups, was achieved by performing X-ray diffraction studies, NMR spectroscopy, and other calculations. The stereochemical complexity is determined by the different isomers formed through complexation of the metal to one or other face of each of the three olefins involved. The pallada-cyclopropane formulation of the palladium-olefin interaction offers a clear picture of the stereogenicity of the olefin carbon atoms that are complexed to the metal. The energetically favorable isomers were identified in the solid-state and in solution by performing X-ray diffraction and NMR spectroscopic analysis, respectively. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA. Weinheim.
Original languageEnglish
Pages (from-to)2689-2697
JournalChemistry - A European Journal
Volume11
Issue number9
DOIs
Publication statusPublished - 22 Apr 2005

Keywords

  • Alkene ligands
  • Macrocycles
  • Palladium
  • Stereoisomers
  • Structure elucidation

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