Strong 1,4-P-O intramolecular interactions as a source of conformational preferences in α-stabilized phosphorus ylides

A. Lledós, J. J. Carbó, E. P. Urriolabeitia

Research output: Contribution to journalArticleResearchpeer-review

33 Citations (Scopus)

Abstract

For the first time, the existence of a strong intramolecular 1,4-interaction between the phosphorus atom and the oxygen atom in α-keto-stabilized ylides has been demonstrated by means of theoretical calculations. This interaction has a notable influence on the conformational preferences and rotational barriers of α-stabilized phosphorus ylides and bis-ylides.
Original languageEnglish
Pages (from-to)4913-4917
JournalInorganic Chemistry
Volume40
Issue number19
DOIs
Publication statusPublished - 10 Sep 2001

Fingerprint

Dive into the research topics of 'Strong 1,4-P-O intramolecular interactions as a source of conformational preferences in α-stabilized phosphorus ylides'. Together they form a unique fingerprint.

Cite this