Stereoselective free-radical cyclization on a sugar template the sulphonyl radical as a synthetic tool for functionalized glycosides

Robert Nouguier, Catherine Lesueur, Enzo De Riggi, Michèle Paula Bertrand, Albert Virgili

Research output: Contribution to journalArticleResearchpeer-review

35 Citations (Scopus)

Abstract

The addition of a sulphonyl radical to the external double bond of an allyl glycal generates a pro-chiral carbon radical which adds to the glycal double bond with a high diastereoselectivity. Through three consecutive radical steps, the configurations of three new asymmetric centers are controlled. © 1990.
Original languageEnglish
Pages (from-to)3541-3544
JournalTetrahedron Letters
Volume31
Issue number25
DOIs
Publication statusPublished - 1 Jan 1990

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