Stereocontrolled synthesis of (3s,4s,5s)-3-alkyl-4-hydroxy-5-methyl-2(3h)-dihydrofubanones and derivatives. Configurational assignment of some clinostemon mahuba and plexaura flava metabolites

Rosa M. Ortuño; Joaquim Bigorra; Josep Font

doi:10.1016/S0040-4020(01)86019-1

Stereocontrolled synthesis of (3s,4s,5s)-3-alkyl-4-hydroxy-5-methyl-2(3h)-dihydrofubanones and derivatives. Configurational assignment of some clinostemon mahuba and plexaura flava metabolites

Rosa M. Ortuño, Joaquim Bigorra, Josep Font

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

25 Citations (Scopus)

Abstract

Absolute and relative configuration has been assigned to some metabolites from mahuba tree and the coral Plexaura flava, by enantio- and diastereo-controlled synthesis of (3S,4S,5S)-3-alkyl-4-hydroxy-5-methyl-2(3H)-dihydrofura-nones and their acetyl derivativatives, (S)-lactic acid being used as chiral precursor. © 1988.

Original language	English
Pages (from-to)	5139-5144
Journal	Tetrahedron
Volume	44
Issue number	16
DOIs	https://doi.org/10.1016/S0040-4020(01)86019-1
Publication status	Published - 1 Jan 1988

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title = "Stereocontrolled synthesis of (3s,4s,5s)-3-alkyl-4-hydroxy-5-methyl-2(3h)-dihydrofubanones and derivatives. Configurational assignment of some clinostemon mahuba and plexaura flava metabolites",

abstract = "Absolute and relative configuration has been assigned to some metabolites from mahuba tree and the coral Plexaura flava, by enantio- and diastereo-controlled synthesis of (3S,4S,5S)-3-alkyl-4-hydroxy-5-methyl-2(3H)-dihydrofura-nones and their acetyl derivativatives, (S)-lactic acid being used as chiral precursor. {\textcopyright} 1988.",

author = "Ortu{\~n}o, {Rosa M.} and Joaquim Bigorra and Josep Font",

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Stereocontrolled synthesis of (3s,4s,5s)-3-alkyl-4-hydroxy-5-methyl-2(3h)-dihydrofubanones and derivatives. Configurational assignment of some clinostemon mahuba and plexaura flava metabolites. / Ortuño, Rosa M.; Bigorra, Joaquim; Font, Josep.

In: Tetrahedron, Vol. 44, No. 16, 01.01.1988, p. 5139-5144.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Stereocontrolled synthesis of (3s,4s,5s)-3-alkyl-4-hydroxy-5-methyl-2(3h)-dihydrofubanones and derivatives. Configurational assignment of some clinostemon mahuba and plexaura flava metabolites

AU - Ortuño, Rosa M.

AU - Bigorra, Joaquim

AU - Font, Josep

PY - 1988/1/1

Y1 - 1988/1/1

N2 - Absolute and relative configuration has been assigned to some metabolites from mahuba tree and the coral Plexaura flava, by enantio- and diastereo-controlled synthesis of (3S,4S,5S)-3-alkyl-4-hydroxy-5-methyl-2(3H)-dihydrofura-nones and their acetyl derivativatives, (S)-lactic acid being used as chiral precursor. © 1988.

AB - Absolute and relative configuration has been assigned to some metabolites from mahuba tree and the coral Plexaura flava, by enantio- and diastereo-controlled synthesis of (3S,4S,5S)-3-alkyl-4-hydroxy-5-methyl-2(3H)-dihydrofura-nones and their acetyl derivativatives, (S)-lactic acid being used as chiral precursor. © 1988.

U2 - 10.1016/S0040-4020(01)86019-1

DO - 10.1016/S0040-4020(01)86019-1

M3 - Article

VL - 44

SP - 5139

EP - 5144

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

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