TY - JOUR
T1 - Stabilization of an anionic guest adsorbed on sodium faujasites through enhanced Coulombic interaction
AU - Raul Herance, José
AU - Marquet, Jordi
AU - Luis Bourdelande, José
AU - García, Hermenegildo
PY - 2004/9/1
Y1 - 2004/9/1
N2 - The negatively charged adduct formed by reaction of 2,4-dinitroaniline with NaBH4 (Meisenheimer complex) has been successfully incorporated inside faujasites. The internal location of the anionic Meisenheimer guest was confirmed by XPS. This anionic reaction intermediate becomes largely stabilized by the inclusion in zeolite as the result of an increase of the association constant with alkali metal ions inside the zeolite cavities. © 2004 Elsevier B.V. All rights reserved.
AB - The negatively charged adduct formed by reaction of 2,4-dinitroaniline with NaBH4 (Meisenheimer complex) has been successfully incorporated inside faujasites. The internal location of the anionic Meisenheimer guest was confirmed by XPS. This anionic reaction intermediate becomes largely stabilized by the inclusion in zeolite as the result of an increase of the association constant with alkali metal ions inside the zeolite cavities. © 2004 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.cplett.2004.07.048
DO - 10.1016/j.cplett.2004.07.048
M3 - Article
SN - 0009-2614
VL - 395
SP - 49
EP - 52
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-3
ER -