TY - JOUR
T1 - Stability constants of palladium(II) complexes with thio- and dithiodiacids
AU - Coello, J.
AU - Hernández Cassou, S.
AU - Martínez, H. Iturriaga
PY - 1986/1/1
Y1 - 1986/1/1
N2 - The formation of complexes between palladium(II) and 3,3′-thiodipropanoic (TDPA) and 3,3′-dithiodipropanoic (DTDPA) acids has been studied by using spectrophotometric methods in acidic aqueous media with a constant ionic strength of 0.5 M (Na+, H+)ClO-4. The stoichiometry of the detected complexes is 1:1 and 1:2 (metal:ligand) for the Pd-TDPA system, and 2:1 and 1:1 for the Pd-DTDPA system. The spectrophotometric characteristics and equilibrium constants for the different species have been calculated with the LETAGROP-SPEFO computer program. © 1986.
AB - The formation of complexes between palladium(II) and 3,3′-thiodipropanoic (TDPA) and 3,3′-dithiodipropanoic (DTDPA) acids has been studied by using spectrophotometric methods in acidic aqueous media with a constant ionic strength of 0.5 M (Na+, H+)ClO-4. The stoichiometry of the detected complexes is 1:1 and 1:2 (metal:ligand) for the Pd-TDPA system, and 2:1 and 1:1 for the Pd-DTDPA system. The spectrophotometric characteristics and equilibrium constants for the different species have been calculated with the LETAGROP-SPEFO computer program. © 1986.
U2 - 10.1016/S0277-5387(00)84856-1
DO - 10.1016/S0277-5387(00)84856-1
M3 - Article
VL - 5
SP - 1777
EP - 1784
IS - 11
ER -