Spin coupling and relaxation inside moleculeĝ€"metal contacts

Aitor Mugarza, Cornelius Krull, Roberto Robles, Sebastian Stepanow, Gustavo Ceballos, Pietro Gambardella

Research output: Contribution to journalArticleResearchpeer-review

123 Citations (Scopus)

Abstract

Advances in molecular electronics depend on the ability to control the charge and spin of single molecules at the interface with a metal. Here we show that bonding of metalĝ€"organic complexes to a metallic substrate induces the formation of coupled metalĝ€"ligand spin states, increasing the spin degeneracy of the molecules and opening multiple spin relaxation channels. Scanning tunnelling spectroscopy reveals the sign and magnitude of intramolecular exchange coupling as well as the orbital character of the spin-polarized molecular states. We observe coexisting Kondo, spin, and vibrational inelastic channels in a single molecule, which lead to pronounced intramolecular variations of the conductance and spin dynamics. The spin degeneracy of the molecules can be controlled by artificially fabricating molecular clusters of different size and shape. By comparing data for vibronic and spin-exchange excitations, we provide a positive test of the universal scaling properties of inelastic Kondo processes having different physical origin. © 2011 Macmillan Publishers Limited. All rights reserved.
Original languageEnglish
Article number490
JournalNature Communications
Volume2
Issue number1
DOIs
Publication statusPublished - 2 Nov 2011

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