Solvent effects on the polarographic behaviour of halobenzenes in aprotic media

J. Casado; J. Domenech; I. Gallardo

doi:10.1007/BF00809345

Solvent effects on the polarographic behaviour of halobenzenes in aprotic media

J. Casado, J. Domenech, I. Gallardo

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

16 Citations (Scopus)

Abstract

The polarographic behaviour of fluoro, chloro, bromo and iodobenzene in dimethylformamide, dimethylsulfoxide and acetonitrile at 25 °C is reported. The viscosities and densities of these species in the three solvents have been measured and the corresponding viscosity B-coefficients and molar partial volumes at infinite dilution for halobenzenes are reported. The results, which show a clear dependence upon solvent nature, are analysed in terms of solute-solvent interactions and solvent structure. © 1984 Springer-Verlag.

Original language	English
Pages (from-to)	1143-1149
Journal	Monatshefte für Chemie Chemical Monthly
Volume	115
Issue number	10
DOIs	https://doi.org/10.1007/BF00809345
Publication status	Published - 1 Oct 1984

Keywords

Aprotic solvents
Diffusion
Halobenzenes

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title = "Solvent effects on the polarographic behaviour of halobenzenes in aprotic media",

abstract = "The polarographic behaviour of fluoro, chloro, bromo and iodobenzene in dimethylformamide, dimethylsulfoxide and acetonitrile at 25 °C is reported. The viscosities and densities of these species in the three solvents have been measured and the corresponding viscosity B-coefficients and molar partial volumes at infinite dilution for halobenzenes are reported. The results, which show a clear dependence upon solvent nature, are analysed in terms of solute-solvent interactions and solvent structure. {\textcopyright} 1984 Springer-Verlag.",

keywords = "Aprotic solvents, Diffusion, Halobenzenes",

author = "J. Casado and J. Domenech and I. Gallardo",

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T1 - Solvent effects on the polarographic behaviour of halobenzenes in aprotic media

AU - Casado, J.

AU - Domenech, J.

AU - Gallardo, I.

PY - 1984/10/1

Y1 - 1984/10/1

N2 - The polarographic behaviour of fluoro, chloro, bromo and iodobenzene in dimethylformamide, dimethylsulfoxide and acetonitrile at 25 °C is reported. The viscosities and densities of these species in the three solvents have been measured and the corresponding viscosity B-coefficients and molar partial volumes at infinite dilution for halobenzenes are reported. The results, which show a clear dependence upon solvent nature, are analysed in terms of solute-solvent interactions and solvent structure. © 1984 Springer-Verlag.

AB - The polarographic behaviour of fluoro, chloro, bromo and iodobenzene in dimethylformamide, dimethylsulfoxide and acetonitrile at 25 °C is reported. The viscosities and densities of these species in the three solvents have been measured and the corresponding viscosity B-coefficients and molar partial volumes at infinite dilution for halobenzenes are reported. The results, which show a clear dependence upon solvent nature, are analysed in terms of solute-solvent interactions and solvent structure. © 1984 Springer-Verlag.

KW - Aprotic solvents

KW - Diffusion

KW - Halobenzenes

U2 - 10.1007/BF00809345

DO - 10.1007/BF00809345

M3 - Article

VL - 115

SP - 1143

EP - 1149

IS - 10

ER -