The polarographic behaviour of fluoro, chloro, bromo and iodobenzene in dimethylformamide, dimethylsulfoxide and acetonitrile at 25 °C is reported. The viscosities and densities of these species in the three solvents have been measured and the corresponding viscosity B-coefficients and molar partial volumes at infinite dilution for halobenzenes are reported. The results, which show a clear dependence upon solvent nature, are analysed in terms of solute-solvent interactions and solvent structure. © 1984 Springer-Verlag.
|Journal||Monatshefte fur Chemie|
|Publication status||Published - 1 Oct 1984|
- Aprotic solvents