Solvent effect in the Diels-Alder reaction

L. Pardo; V. Branchadell; A. Oliva; J. Bertrán

doi:10.1016/0166-1280(83)80109-2

Solvent effect in the Diels-Alder reaction

L. Pardo, V. Branchadell, A. Oliva, J. Bertrán

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Abstract

The solvent effect on the rate constant, regioselectivity and stereoselectivity of the Diels-Alder reaction between 1-hydroxybutadiene and crolein has been studied theoretically by means of the cavity model. The results obtained are in good agreement with the experimental facts. The fundamental role of charge transfer in the increase of selectivity with the solvent is discussed. © 1983.

Original language	English
Pages (from-to)	255-260
Journal	Journal of Molecular Structure: THEOCHEM
Volume	93
Issue number	C
DOIs	https://doi.org/10.1016/0166-1280(83)80109-2
Publication status	Published - 1 Jan 1983

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title = "Solvent effect in the Diels-Alder reaction",

abstract = "The solvent effect on the rate constant, regioselectivity and stereoselectivity of the Diels-Alder reaction between 1-hydroxybutadiene and crolein has been studied theoretically by means of the cavity model. The results obtained are in good agreement with the experimental facts. The fundamental role of charge transfer in the increase of selectivity with the solvent is discussed. {\textcopyright} 1983.",

author = "L. Pardo and V. Branchadell and A. Oliva and J. Bertr{\'a}n",

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AU - Pardo, L.

AU - Branchadell, V.

AU - Oliva, A.

AU - Bertrán, J.

PY - 1983/1/1

Y1 - 1983/1/1

N2 - The solvent effect on the rate constant, regioselectivity and stereoselectivity of the Diels-Alder reaction between 1-hydroxybutadiene and crolein has been studied theoretically by means of the cavity model. The results obtained are in good agreement with the experimental facts. The fundamental role of charge transfer in the increase of selectivity with the solvent is discussed. © 1983.

AB - The solvent effect on the rate constant, regioselectivity and stereoselectivity of the Diels-Alder reaction between 1-hydroxybutadiene and crolein has been studied theoretically by means of the cavity model. The results obtained are in good agreement with the experimental facts. The fundamental role of charge transfer in the increase of selectivity with the solvent is discussed. © 1983.

U2 - 10.1016/0166-1280(83)80109-2

DO - 10.1016/0166-1280(83)80109-2

M3 - Article

VL - 93

SP - 255

EP - 260

IS - C

ER -

Solvent effect in the Diels-Alder reaction

Abstract

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