Solvent effect in the Diels-Alder reaction

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Abstract

The solvent effect on the rate constant, regioselectivity and stereoselectivity of the Diels-Alder reaction between 1-hydroxybutadiene and crolein has been studied theoretically by means of the cavity model. The results obtained are in good agreement with the experimental facts. The fundamental role of charge transfer in the increase of selectivity with the solvent is discussed. © 1983.
Original languageEnglish
Pages (from-to)255-260
JournalJournal of Molecular Structure: THEOCHEM
Volume93
Issue numberC
DOIs
Publication statusPublished - 1 Jan 1983

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