Solid state and theoretical conformational analysis of enantiopure C2 symmetric bis(α,β-butenolides)

Pedro De March, Marta Figueredo, Josep Font, Javier Raya, Angel Alvarez-Larena, Juan F. Piniella

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1 Citation (Scopus)

Abstract

The solid state structure and theoretical conformational analysis of two enantiomerically pure bis(α,β-butenolides) with C2 symmetry have been performed. The crystal structure and calculated geometries are in very good agreement with the diastereofacial selectivity observed for these compounds in their [2 + 2] photocycloaddition to ethylene. © 2003 Elsevier Science B.V. All rights reserved.
Original languageEnglish
Pages (from-to)69-74
JournalJournal of Molecular Structure
Volume648
Issue number1-2
DOIs
Publication statusPublished - 12 Mar 2003

Keywords

  • Bis(α,β-butenolides)
  • C symmetry 2
  • Conformational analysis
  • Diastereoselectivity

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