Size-selective encapsulation of C <inf>60</inf> and C <inf>60</inf> -derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule

Cristina García-Simón; Alba Monferrer; Marc Garcia-Borràs; Inhar Imaz; Daniel Maspoch; Miquel Costas; Xavi Ribas

doi:https://doi.org/10.1039/c8cc07886f

Size-selective encapsulation of C <inf>60</inf> and C <inf>60</inf> -derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule

Cristina García-Simón, Alba Monferrer, Marc Garcia-Borràs, Inhar Imaz, Daniel Maspoch, Miquel Costas, Xavi Ribas

Research output: Contribution to journal › Article › Research

9 Citations (Scopus)

Abstract

© The Royal Society of Chemistry. A novel naphthalene-based 5·(BArF) 8 capsule allows for the size-selective inclusion of C 60 from fullerene mixtures. Its size selectivity towards C 60 has been rationalized by its dynamic adaptability in solution that has been investigated by molecular dynamics. Additionally, 5·(BArF) 8 encapsulates C 60 -derivatives such as C 60 -PCBM and N-methylpyrrolidine-C 60 . The latter can be separated from C 60 since 5·(BArF) 8 displays distinct affinity for them.

Original language	English
Pages (from-to)	798-801
Journal	Chemical Communications
Volume	55
DOIs	https://doi.org/10.1039/c8cc07886f
Publication status	Published - 1 Jan 2019

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title = "Size-selective encapsulation of C 60 and C 60 -derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule",

abstract = "{\textcopyright} The Royal Society of Chemistry. A novel naphthalene-based 5·(BArF) 8 capsule allows for the size-selective inclusion of C 60 from fullerene mixtures. Its size selectivity towards C 60 has been rationalized by its dynamic adaptability in solution that has been investigated by molecular dynamics. Additionally, 5·(BArF) 8 encapsulates C 60 -derivatives such as C 60 -PCBM and N-methylpyrrolidine-C 60 . The latter can be separated from C 60 since 5·(BArF) 8 displays distinct affinity for them.",

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year = "2019",

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doi = "https://doi.org/10.1039/c8cc07886f",

language = "English",

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Size-selective encapsulation of C <inf>60</inf> and C <inf>60</inf> -derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule. / García-Simón, Cristina; Monferrer, Alba; Garcia-Borràs, Marc; Imaz, Inhar; Maspoch, Daniel; Costas, Miquel; Ribas, Xavi.

In: Chemical Communications, Vol. 55, 01.01.2019, p. 798-801.

Research output: Contribution to journal › Article › Research

TY - JOUR

T1 - Size-selective encapsulation of C 60 and C 60 -derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule

AU - García-Simón, Cristina

AU - Monferrer, Alba

AU - Garcia-Borràs, Marc

AU - Imaz, Inhar

AU - Maspoch, Daniel

AU - Costas, Miquel

AU - Ribas, Xavi

PY - 2019/1/1

Y1 - 2019/1/1

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AB - © The Royal Society of Chemistry. A novel naphthalene-based 5·(BArF) 8 capsule allows for the size-selective inclusion of C 60 from fullerene mixtures. Its size selectivity towards C 60 has been rationalized by its dynamic adaptability in solution that has been investigated by molecular dynamics. Additionally, 5·(BArF) 8 encapsulates C 60 -derivatives such as C 60 -PCBM and N-methylpyrrolidine-C 60 . The latter can be separated from C 60 since 5·(BArF) 8 displays distinct affinity for them.

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