Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal-Organic Framework via Ozonolysis

Jorge Albalad; Heng Xu; Felipe Gándara; Mohamed Haouas; Charlotte Martineau-Corcos; Rubén Mas-Ballesté; Sarah A. Barnett; Judith Juanhuix; Inhar Imaz; Daniel Maspoch

doi:10.1021/jacs.7b12913

Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal-Organic Framework via Ozonolysis

Jorge Albalad, Heng Xu, Felipe Gándara, Mohamed Haouas, Charlotte Martineau-Corcos, Rubén Mas-Ballesté, Sarah A. Barnett, Judith Juanhuix, Inhar Imaz, Daniel Maspoch

Research output: Contribution to journal › Article › Research › peer-review

52 Citations (Scopus)

Abstract

© 2018 American Chemical Society. We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.

Original language	English
Pages (from-to)	2028-2031
Journal	Journal of the American Chemical Society
Volume	140
Issue number	6
DOIs	https://doi.org/10.1021/jacs.7b12913
Publication status	Published - 14 Feb 2018

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10.1021/jacs.7b12913

https://ddd.uab.cat/record/206933

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title = "Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal-Organic Framework via Ozonolysis",

abstract = "{\textcopyright} 2018 American Chemical Society. We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.",

author = "Jorge Albalad and Heng Xu and Felipe G{\'a}ndara and Mohamed Haouas and Charlotte Martineau-Corcos and Rub{\'e}n Mas-Ballest{\'e} and Barnett, \{Sarah A.\} and Judith Juanhuix and Inhar Imaz and Daniel Maspoch",

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doi = "10.1021/jacs.7b12913",

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T1 - Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal-Organic Framework via Ozonolysis

AU - Albalad, Jorge

AU - Xu, Heng

AU - Gándara, Felipe

AU - Haouas, Mohamed

AU - Martineau-Corcos, Charlotte

AU - Mas-Ballesté, Rubén

AU - Barnett, Sarah A.

AU - Juanhuix, Judith

AU - Imaz, Inhar

AU - Maspoch, Daniel

PY - 2018/2/14

Y1 - 2018/2/14

N2 - © 2018 American Chemical Society. We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.

AB - © 2018 American Chemical Society. We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.

UR - https://www.scopus.com/pages/publications/85042053614

U2 - 10.1021/jacs.7b12913

DO - 10.1021/jacs.7b12913

M3 - Article

SN - 0002-7863

VL - 140

SP - 2028

EP - 2031

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 6

ER -

Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal-Organic Framework via Ozonolysis

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