Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal-Organic Framework via Ozonolysis

Jorge Albalad, Heng Xu, Felipe Gándara, Mohamed Haouas, Charlotte Martineau-Corcos, Rubén Mas-Ballesté, Sarah A. Barnett, Judith Juanhuix, Inhar Imaz, Daniel Maspoch

    Research output: Contribution to journalArticleResearchpeer-review

    13 Citations (Scopus)

    Abstract

    © 2018 American Chemical Society. We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.
    Original languageEnglish
    Pages (from-to)2028-2031
    JournalJournal of the American Chemical Society
    Volume140
    Issue number6
    DOIs
    Publication statusPublished - 14 Feb 2018

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