Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption

Javier Aríñez-Soriano; Jorge Albalad; Christian Vila-Parrondo; Javier Pérez-Carvajal; Sabina Rodríguez-Hermida; Aurelio Cabeza; Jordi Juanhuix; Inhar Imaz; Daniel Maspoch

doi:10.1039/c6cc02908f

Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption

Javier Aríñez-Soriano, Jorge Albalad, Christian Vila-Parrondo, Javier Pérez-Carvajal, Sabina Rodríguez-Hermida, Aurelio Cabeza, Jordi Juanhuix, Inhar Imaz, Daniel Maspoch

Research output: Contribution to journal › Article › Research › peer-review

10 Citations (Scopus)

Abstract

© 2016 The Royal Society of Chemistry. Herein we report a study on water adsorption/desorption-triggered single-crystal to single-crystal transformations in a MOF, by single-crystal and humidity-controlled powder X-ray diffraction and water-sorption measurements. We identified a gate-opening effect at a relative humidity of 85% upon water adsorption, and a gate-closure effect at a relative humidity of 55 to 77% upon water desorption. This reversible breathing effect between the "open" and the "closed" structures of the MOF involves the cleavage and formation of several coordination bonds.

Original language	English
Pages (from-to)	7229-7232
Journal	Chemical Communications
Volume	52
Issue number	45
DOIs	https://doi.org/10.1039/c6cc02908f
Publication status	Published - 1 Jan 2016

Access to Document

10.1039/c6cc02908f

Fingerprint Dive into the research topics of 'Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption'. Together they form a unique fingerprint.

Cite this

Aríñez-Soriano, J., Albalad, J., Vila-Parrondo, C., Pérez-Carvajal, J., Rodríguez-Hermida, S., Cabeza, A., Juanhuix, J., Imaz, I., & Maspoch, D. (2016). Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption. Chemical Communications, 52(45), 7229-7232. https://doi.org/10.1039/c6cc02908f

Aríñez-Soriano, Javier ; Albalad, Jorge ; Vila-Parrondo, Christian ; Pérez-Carvajal, Javier ; Rodríguez-Hermida, Sabina ; Cabeza, Aurelio ; Juanhuix, Jordi ; Imaz, Inhar ; Maspoch, Daniel. / Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption. In: Chemical Communications. 2016 ; Vol. 52, No. 45. pp. 7229-7232.

@article{5a01481ee953480bbcce8a789a768cdc,

title = "Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption",

abstract = "{\textcopyright} 2016 The Royal Society of Chemistry. Herein we report a study on water adsorption/desorption-triggered single-crystal to single-crystal transformations in a MOF, by single-crystal and humidity-controlled powder X-ray diffraction and water-sorption measurements. We identified a gate-opening effect at a relative humidity of 85% upon water adsorption, and a gate-closure effect at a relative humidity of 55 to 77% upon water desorption. This reversible breathing effect between the {"}open{"} and the {"}closed{"} structures of the MOF involves the cleavage and formation of several coordination bonds.",

author = "Javier Ar{\'i}{\~n}ez-Soriano and Jorge Albalad and Christian Vila-Parrondo and Javier P{\'e}rez-Carvajal and Sabina Rodr{\'i}guez-Hermida and Aurelio Cabeza and Jordi Juanhuix and Inhar Imaz and Daniel Maspoch",

year = "2016",

month = jan,

day = "1",

doi = "10.1039/c6cc02908f",

language = "English",

volume = "52",

pages = "7229--7232",

number = "45",

}

Aríñez-Soriano, J, Albalad, J, Vila-Parrondo, C, Pérez-Carvajal, J, Rodríguez-Hermida, S, Cabeza, A, Juanhuix, J, Imaz, I & Maspoch, D 2016, 'Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption', Chemical Communications, vol. 52, no. 45, pp. 7229-7232. https://doi.org/10.1039/c6cc02908f

Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption. / Aríñez-Soriano, Javier; Albalad, Jorge; Vila-Parrondo, Christian; Pérez-Carvajal, Javier; Rodríguez-Hermida, Sabina; Cabeza, Aurelio; Juanhuix, Jordi; Imaz, Inhar; Maspoch, Daniel.

In: Chemical Communications, Vol. 52, No. 45, 01.01.2016, p. 7229-7232.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Single-crystal and humidity-controlled powder diffraction study of the breathing effect in a metal-organic framework upon water adsorption/desorption

AU - Aríñez-Soriano, Javier

AU - Albalad, Jorge

AU - Vila-Parrondo, Christian

AU - Pérez-Carvajal, Javier

AU - Rodríguez-Hermida, Sabina

AU - Cabeza, Aurelio

AU - Juanhuix, Jordi

AU - Imaz, Inhar

AU - Maspoch, Daniel

PY - 2016/1/1

Y1 - 2016/1/1

N2 - © 2016 The Royal Society of Chemistry. Herein we report a study on water adsorption/desorption-triggered single-crystal to single-crystal transformations in a MOF, by single-crystal and humidity-controlled powder X-ray diffraction and water-sorption measurements. We identified a gate-opening effect at a relative humidity of 85% upon water adsorption, and a gate-closure effect at a relative humidity of 55 to 77% upon water desorption. This reversible breathing effect between the "open" and the "closed" structures of the MOF involves the cleavage and formation of several coordination bonds.

AB - © 2016 The Royal Society of Chemistry. Herein we report a study on water adsorption/desorption-triggered single-crystal to single-crystal transformations in a MOF, by single-crystal and humidity-controlled powder X-ray diffraction and water-sorption measurements. We identified a gate-opening effect at a relative humidity of 85% upon water adsorption, and a gate-closure effect at a relative humidity of 55 to 77% upon water desorption. This reversible breathing effect between the "open" and the "closed" structures of the MOF involves the cleavage and formation of several coordination bonds.

U2 - 10.1039/c6cc02908f

DO - 10.1039/c6cc02908f

M3 - Article

VL - 52

SP - 7229

EP - 7232

IS - 45

ER -