Simultaneous Titration of Ternary Mixtures of Pb(II), Cd(II) and Cu(II) with Potentiometric Electronic Tongue Detection

Deivy Wilson; Salvador Alegret; Manel delValle

doi:https://doi.org/10.1002/elan.201400480

Simultaneous Titration of Ternary Mixtures of Pb(II), Cd(II) and Cu(II) with Potentiometric Electronic Tongue Detection

Deivy Wilson, Salvador Alegret, Manel delValle

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

6 Citations (Scopus)

Abstract

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. An automatic titration method is reported to resolve ternary mixtures of transition metals (Pb2+, Cd2+ and Cu2+) employing electronic tongue detection and a reduced number of pre-defined additions of EDTA titrant. Sensors used were PVC membrane selective electrodes with generic response to heavy-metals, plus an artificial neural network response model. Detection limits obtained were ca. 1 mg L-1 for the three target ions and reproducibilities 3.0% for Pb2+, 4.1% for Cd2+ and 5.2% for Cu2+. The system was applied to contaminated soil samples and high accuracy was obtained for the determination of Pb2+. In the determination Cd2+ and Cu2+, sample matrix showed a significant effect.

Original language	English
Pages (from-to)	336-342
Journal	Electroanalysis
Volume	27
Issue number	2
DOIs	https://doi.org/10.1002/elan.201400480
Publication status	Published - 1 Jan 2015

Keywords

Artificial neural networks
Electronic tongue
Ion selective electrodes
Sensor array
Simultaneous titration
Transition metals

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https://doi.org/10.1002/elan.201400480

https://ddd.uab.cat/record/144741Licence: CC BY-NC-ND

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title = "Simultaneous Titration of Ternary Mixtures of Pb(II), Cd(II) and Cu(II) with Potentiometric Electronic Tongue Detection",

abstract = "{\textcopyright} 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. An automatic titration method is reported to resolve ternary mixtures of transition metals (Pb2+, Cd2+ and Cu2+) employing electronic tongue detection and a reduced number of pre-defined additions of EDTA titrant. Sensors used were PVC membrane selective electrodes with generic response to heavy-metals, plus an artificial neural network response model. Detection limits obtained were ca. 1 mg L-1 for the three target ions and reproducibilities 3.0% for Pb2+, 4.1% for Cd2+ and 5.2% for Cu2+. The system was applied to contaminated soil samples and high accuracy was obtained for the determination of Pb2+. In the determination Cd2+ and Cu2+, sample matrix showed a significant effect.",

keywords = "Artificial neural networks, Electronic tongue, Ion selective electrodes, Sensor array, Simultaneous titration, Transition metals",

author = "Deivy Wilson and Salvador Alegret and Manel delValle",

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doi = "https://doi.org/10.1002/elan.201400480",

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T1 - Simultaneous Titration of Ternary Mixtures of Pb(II), Cd(II) and Cu(II) with Potentiometric Electronic Tongue Detection

AU - Wilson, Deivy

AU - Alegret, Salvador

AU - delValle, Manel

PY - 2015/1/1

Y1 - 2015/1/1

N2 - © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. An automatic titration method is reported to resolve ternary mixtures of transition metals (Pb2+, Cd2+ and Cu2+) employing electronic tongue detection and a reduced number of pre-defined additions of EDTA titrant. Sensors used were PVC membrane selective electrodes with generic response to heavy-metals, plus an artificial neural network response model. Detection limits obtained were ca. 1 mg L-1 for the three target ions and reproducibilities 3.0% for Pb2+, 4.1% for Cd2+ and 5.2% for Cu2+. The system was applied to contaminated soil samples and high accuracy was obtained for the determination of Pb2+. In the determination Cd2+ and Cu2+, sample matrix showed a significant effect.

AB - © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. An automatic titration method is reported to resolve ternary mixtures of transition metals (Pb2+, Cd2+ and Cu2+) employing electronic tongue detection and a reduced number of pre-defined additions of EDTA titrant. Sensors used were PVC membrane selective electrodes with generic response to heavy-metals, plus an artificial neural network response model. Detection limits obtained were ca. 1 mg L-1 for the three target ions and reproducibilities 3.0% for Pb2+, 4.1% for Cd2+ and 5.2% for Cu2+. The system was applied to contaminated soil samples and high accuracy was obtained for the determination of Pb2+. In the determination Cd2+ and Cu2+, sample matrix showed a significant effect.

KW - Artificial neural networks

KW - Electronic tongue

KW - Ion selective electrodes

KW - Sensor array

KW - Simultaneous titration

KW - Transition metals

U2 - https://doi.org/10.1002/elan.201400480

DO - https://doi.org/10.1002/elan.201400480

M3 - Article

SN - 1040-0397

VL - 27

SP - 336

EP - 342

JO - Electroanalysis

JF - Electroanalysis

IS - 2

ER -

Simultaneous Titration of Ternary Mixtures of Pb(II), Cd(II) and Cu(II) with Potentiometric Electronic Tongue Detection

Abstract

Keywords

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