Simultaneous Synthesis of Cis and Trans Difluorobisdiaminechromium(III) Complexes

J. Casabó, A. Solans

Research output: Contribution to journalArticleResearchpeer-review

3 Citations (Scopus)

Abstract

In this paper we report on the simultaneous synthesis of cis and trans complexes of the type: [crF2 (diamine)2]+] (diamine - ethylenediamine(en) and 1,2-propanediamine(pn)# The cis species are considerably more soluble than the trans. As a consequence, the last one is easily removed from the reaction mixture. We suggest a cis-complex formation from a trans → cis isomerization. This increases as the reaction time increases. © 1983, Taylor & Francis Group, LLC. All rights reserved.
Original languageEnglish
Pages (from-to)835-842
JournalSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume13
Issue number7
DOIs
Publication statusPublished - 1 Jan 1983

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