TY - JOUR
T1 - Simultaneous Synthesis of Cis and Trans Difluorobisdiaminechromium(III) Complexes
AU - Casabó, J.
AU - Solans, A.
PY - 1983/1/1
Y1 - 1983/1/1
N2 - In this paper we report on the simultaneous synthesis of cis and trans complexes of the type: [crF2 (diamine)2]+] (diamine - ethylenediamine(en) and 1,2-propanediamine(pn)# The cis species are considerably more soluble than the trans. As a consequence, the last one is easily removed from the reaction mixture. We suggest a cis-complex formation from a trans → cis isomerization. This increases as the reaction time increases. © 1983, Taylor & Francis Group, LLC. All rights reserved.
AB - In this paper we report on the simultaneous synthesis of cis and trans complexes of the type: [crF2 (diamine)2]+] (diamine - ethylenediamine(en) and 1,2-propanediamine(pn)# The cis species are considerably more soluble than the trans. As a consequence, the last one is easily removed from the reaction mixture. We suggest a cis-complex formation from a trans → cis isomerization. This increases as the reaction time increases. © 1983, Taylor & Francis Group, LLC. All rights reserved.
U2 - 10.1080/00945718308059346
DO - 10.1080/00945718308059346
M3 - Article
SN - 0094-5714
VL - 13
SP - 835
EP - 842
JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
IS - 7
ER -