Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst

Thibault Troadec; Amparo Prades; Ricardo Rodriguez; Raphael Mirgalet; Antoine Baceiredo; Nathalie Saffon-Merceron; Vicenç Branchadell; Tsuyoshi Kato

doi:10.1021/acs.inorgchem.6b01505

Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst

Thibault Troadec, Amparo Prades, Ricardo Rodriguez, Raphael Mirgalet, Antoine Baceiredo, Nathalie Saffon-Merceron, Vicenç Branchadell, Tsuyoshi Kato

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Abstract

© 2016 American Chemical Society. The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic ligand toward transition metals. The strong silylene-metal binding related to both increased σ-donating and π-accepting character of silylene 1 compared to N-heterocyclic carbenes (NHCs) allowed the synthesis of robust and air-stable silylene complexes. Of particular interest, the corresponding platinum(0) complex 6 exhibits high stability and a high level of selectivity and catalytic activity in hydrosilylation reactions that is superior to that of the related NHC-Pt0 complexes.

Original language	English
Pages (from-to)	8234-8240
Journal	Inorganic Chemistry
Volume	55
Issue number	16
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01505
Publication status	Published - 15 Aug 2016

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title = "Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst",

abstract = "{\textcopyright} 2016 American Chemical Society. The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic ligand toward transition metals. The strong silylene-metal binding related to both increased σ-donating and π-accepting character of silylene 1 compared to N-heterocyclic carbenes (NHCs) allowed the synthesis of robust and air-stable silylene complexes. Of particular interest, the corresponding platinum(0) complex 6 exhibits high stability and a high level of selectivity and catalytic activity in hydrosilylation reactions that is superior to that of the related NHC-Pt0 complexes.",

author = "Thibault Troadec and Amparo Prades and Ricardo Rodriguez and Raphael Mirgalet and Antoine Baceiredo and Nathalie Saffon-Merceron and Vicen{\c c} Branchadell and Tsuyoshi Kato",

year = "2016",

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doi = "10.1021/acs.inorgchem.6b01505",

language = "English",

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T1 - Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst

AU - Troadec, Thibault

AU - Prades, Amparo

AU - Rodriguez, Ricardo

AU - Mirgalet, Raphael

AU - Baceiredo, Antoine

AU - Saffon-Merceron, Nathalie

AU - Branchadell, Vicenç

AU - Kato, Tsuyoshi

PY - 2016/8/15

Y1 - 2016/8/15

N2 - © 2016 American Chemical Society. The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic ligand toward transition metals. The strong silylene-metal binding related to both increased σ-donating and π-accepting character of silylene 1 compared to N-heterocyclic carbenes (NHCs) allowed the synthesis of robust and air-stable silylene complexes. Of particular interest, the corresponding platinum(0) complex 6 exhibits high stability and a high level of selectivity and catalytic activity in hydrosilylation reactions that is superior to that of the related NHC-Pt0 complexes.

AB - © 2016 American Chemical Society. The base-stabilized silacyclopropylidene 1 behaves as a versatile strongly nucleophilic ligand toward transition metals. The strong silylene-metal binding related to both increased σ-donating and π-accepting character of silylene 1 compared to N-heterocyclic carbenes (NHCs) allowed the synthesis of robust and air-stable silylene complexes. Of particular interest, the corresponding platinum(0) complex 6 exhibits high stability and a high level of selectivity and catalytic activity in hydrosilylation reactions that is superior to that of the related NHC-Pt0 complexes.

U2 - 10.1021/acs.inorgchem.6b01505

DO - 10.1021/acs.inorgchem.6b01505

M3 - Article

VL - 55

SP - 8234

EP - 8240

IS - 16

ER -

Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst

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