Selective picomolar detection of mercury(ii) using optical sensors

César Díez-Gil, Rosario Martínez, Imma Ratera, Thomas Hirsh, Arturo Espinosa, Alberto Tárraga, Pedro Molina, Otto S. Wolfbeis, Jaume Veciana

    Research output: Contribution to journalArticleResearchpeer-review

    41 Citations (Scopus)

    Abstract

    The rational design of a mercury(ii) ligand consisting in a 1-(4′-oxyphenyl)-4(1′-pyrenyl)-2,3-diaza-1,3-butadiene receptor unit, optimizes the sensitivity and reliability of a SPR sensor by the formation of a well packed SAM over the gold surface. SPR analysis allows detecting mercury(ii) concentrations in aqueous systems in the picomolar range, meliorating on three orders of magnitude the EU mercury(ii) detection limit in drinkable water. © 2011 The Royal Society of Chemistry.
    Original languageEnglish
    Pages (from-to)1842-1844
    JournalChemical Communications
    Volume47
    Issue number6
    DOIs
    Publication statusPublished - 14 Feb 2011

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