Selective hydroformylation with a recoverable dirhodium μ-thiolato complex

J. C. Bayón, J. Real, C. Claver, A. Polo, A. Ruiz

Research output: Contribution to journalArticleResearchpeer-review

34 Citations (Scopus)

Abstract

The dimeric precursor complex {Rh<inf>2</inf>[μ-S(CH<inf>2</inf>) <inf>3</inf>N(Me)<inf>2</inf>]<inf>2</inf> (Cod)<inf>2</inf>}, (cod = cyclo-octa-1,5-diene), with PPh<inf>3</inf> catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H <inf>2</inf>SO<inf>4</inf>, and reused without loss of activity.
Original languageEnglish
Pages (from-to)1056-1057
JournalJournal of the Chemical Society D: Chemical Communications
Issue number15
DOIs
Publication statusPublished - 1 Jan 1989

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