Selective hydroformylation with a recoverable dirhodium μ-thiolato complex

J. C. Bayón; J. Real; C. Claver; A. Polo; A. Ruiz

doi:10.1039/C39890001056

Selective hydroformylation with a recoverable dirhodium μ-thiolato complex

J. C. Bayón, J. Real, C. Claver, A. Polo, A. Ruiz

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

34 Citations (Scopus)

Abstract

The dimeric precursor complex {Rh<inf>2</inf>[μ-S(CH<inf>2</inf>) <inf>3</inf>N(Me)<inf>2</inf>]<inf>2</inf> (Cod)<inf>2</inf>}, (cod = cyclo-octa-1,5-diene), with PPh<inf>3</inf> catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H <inf>2</inf>SO<inf>4</inf>, and reused without loss of activity.

Original language	English
Pages (from-to)	1056-1057
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39890001056
Publication status	Published - 1 Jan 1989

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title = "Selective hydroformylation with a recoverable dirhodium μ-thiolato complex",

abstract = "The dimeric precursor complex {Rh2[μ-S(CH2) 3N(Me)2]2 (Cod)2}, (cod = cyclo-octa-1,5-diene), with PPh3 catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H 2SO4, and reused without loss of activity.",

author = "Bay{\'o}n, {J. C.} and J. Real and C. Claver and A. Polo and A. Ruiz",

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AU - Bayón, J. C.

AU - Real, J.

AU - Claver, C.

AU - Polo, A.

AU - Ruiz, A.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - The dimeric precursor complex {Rh2[μ-S(CH2) 3N(Me)2]2 (Cod)2}, (cod = cyclo-octa-1,5-diene), with PPh3 catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H 2SO4, and reused without loss of activity.

AB - The dimeric precursor complex {Rh2[μ-S(CH2) 3N(Me)2]2 (Cod)2}, (cod = cyclo-octa-1,5-diene), with PPh3 catalyses the hydroformylation of hex-1-ene, under mild conditions, into heptanals with high yields and selectivities; owing to the presence of the amine group the rhodium catalyst can be quantitatively recovered from the reaction mixture by adding dilute H 2SO4, and reused without loss of activity.

U2 - 10.1039/C39890001056

DO - 10.1039/C39890001056

M3 - Article

SP - 1056

EP - 1057

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