Sandwich techniques in flow-injection analysis. Part 3. Simultaneous determination of Cr(VI) in two concentration ranges

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Abstract

A flow-injection system based on the sandwich technique is proposed for the determination of Cr(VI). Two simultaneous working ranges of concentration are achieved by appropriate selection of the reagent composition at the two reagent-sample interfaces. The optimized system allows the determination of CR(VI) at levels up to 1 μg ml-1 with a detection limit of 0.01 μg ml-1 for one of the interfaces. for the other, determinations up to 30 μg ml-1 with a detection limit of 0.5 μg ml-1 are possible. The sample throughput achieved was about 45 h-1 with a relative standard deviation <1% in the middle of both ranges. © 1992.
Original languageEnglish
Pages (from-to)219-223
JournalAnalytica Chimica Acta
Volume261
Issue number1-2
DOIs
Publication statusPublished - 25 May 1992

Keywords

  • Chromium
  • Flow system
  • Sandwich techniques
  • Spectrophotometry
  • Waters

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