Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports

Joaquim Mola; Elena Mas-Marza; Xavier Sala; Isabel Romero; Montserrat Rodríguez; Clara Viñas; Teodor Parella; Antoni Llobet

doi:10.1002/anie.200704912

Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports

Joaquim Mola, Elena Mas-Marza, Xavier Sala, Isabel Romero, Montserrat Rodríguez, Clara Viñas, Teodor Parella, Antoni Llobet

Research output: Contribution to journal › Article › Research › peer-review

101 Citations (Scopus)

Abstract

(Figure Presented) Splitting water: Copolymerization of the cationic water-oxidation catalyst [Ru2II(μ-bpp)(t-trpy) 2(H2O)2]3+ (1) with a cobalt cobaltabisdicarbollide monomer (2) generates a new material, "FTO/poly-(1-co-2)", that is capable of oxidizing water to molecular dioxygen with a turnover number (TN) of 250 (see picture). This represents the best performance ever obtained in a heterogeneous phase using a chemical oxidant. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Original language	English
Pages (from-to)	5830-5832
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	31
DOIs	https://doi.org/10.1002/anie.200704912
Publication status	Published - 21 Jul 2008

Keywords

Heterogeneous catalysis
Oxidation
Ruthenium
Water chemistry

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title = "Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports",

abstract = "(Figure Presented) Splitting water: Copolymerization of the cationic water-oxidation catalyst [Ru2II(μ-bpp)(t-trpy) 2(H2O)2]3+ (1) with a cobalt cobaltabisdicarbollide monomer (2) generates a new material, {"}FTO/poly-(1-co-2){"}, that is capable of oxidizing water to molecular dioxygen with a turnover number (TN) of 250 (see picture). This represents the best performance ever obtained in a heterogeneous phase using a chemical oxidant. {\textcopyright} 2008 Wiley-VCH Verlag GmbH & Co. KGaA.",

keywords = "Heterogeneous catalysis, Oxidation, Ruthenium, Water chemistry",

author = "Joaquim Mola and Elena Mas-Marza and Xavier Sala and Isabel Romero and Montserrat Rodr{\'i}guez and Clara Vi{\~n}as and Teodor Parella and Antoni Llobet",

year = "2008",

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language = "English",

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T1 - Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports

AU - Mola, Joaquim

AU - Mas-Marza, Elena

AU - Sala, Xavier

AU - Romero, Isabel

AU - Rodríguez, Montserrat

AU - Viñas, Clara

AU - Parella, Teodor

AU - Llobet, Antoni

PY - 2008/7/21

Y1 - 2008/7/21

N2 - (Figure Presented) Splitting water: Copolymerization of the cationic water-oxidation catalyst [Ru2II(μ-bpp)(t-trpy) 2(H2O)2]3+ (1) with a cobalt cobaltabisdicarbollide monomer (2) generates a new material, "FTO/poly-(1-co-2)", that is capable of oxidizing water to molecular dioxygen with a turnover number (TN) of 250 (see picture). This represents the best performance ever obtained in a heterogeneous phase using a chemical oxidant. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

AB - (Figure Presented) Splitting water: Copolymerization of the cationic water-oxidation catalyst [Ru2II(μ-bpp)(t-trpy) 2(H2O)2]3+ (1) with a cobalt cobaltabisdicarbollide monomer (2) generates a new material, "FTO/poly-(1-co-2)", that is capable of oxidizing water to molecular dioxygen with a turnover number (TN) of 250 (see picture). This represents the best performance ever obtained in a heterogeneous phase using a chemical oxidant. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

KW - Heterogeneous catalysis

KW - Oxidation

KW - Ruthenium

KW - Water chemistry

U2 - 10.1002/anie.200704912

DO - 10.1002/anie.200704912

M3 - Article

SN - 1433-7851

VL - 47

SP - 5830

EP - 5832

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 31

ER -

Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports

Abstract

Keywords

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