Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports

Joaquim Mola, Elena Mas-Marza, Xavier Sala, Isabel Romero, Montserrat Rodríguez, Clara Viñas, Teodor Parella, Antoni Llobet

Research output: Contribution to journalArticleResearchpeer-review

96 Citations (Scopus)

Abstract

(Figure Presented) Splitting water: Copolymerization of the cationic water-oxidation catalyst [Ru2II(μ-bpp)(t-trpy) 2(H2O)2]3+ (1) with a cobalt cobaltabisdicarbollide monomer (2) generates a new material, "FTO/poly-(1-co-2)", that is capable of oxidizing water to molecular dioxygen with a turnover number (TN) of 250 (see picture). This represents the best performance ever obtained in a heterogeneous phase using a chemical oxidant. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
Original languageEnglish
Pages (from-to)5830-5832
JournalAngewandte Chemie - International Edition
Volume47
Issue number31
DOIs
Publication statusPublished - 21 Jul 2008

Keywords

  • Heterogeneous catalysis
  • Oxidation
  • Ruthenium
  • Water chemistry

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