Role of the a1, 3 allylic interaction on the stereochemistry of formation of schiff’s bases derived from bicyclo[2.2.1]hept-5-en-2-one and 7-oxabicyclo[2.2.1]hept-5-en-2-one

Odón Arjona; Araceli Mallo; Cristina Manzano; Joaquín Plumet; Juan Galbis; Carlos Jaime

doi:10.1039/P29880000865

Role of the a^{1, 3} allylic interaction on the stereochemistry of formation of schiff’s bases derived from bicyclo[2.2.1]hept-5-en-2-one and 7-oxabicyclo[2.2.1]hept-5-en-2-one

Odón Arjona, Araceli Mallo, Cristina Manzano, Joaquín Plumet, Juan Galbis, Carlos Jaime

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

5 Citations (Scopus)

Abstract

The stereochemistry of formation of Schiff′s bases de rived from norbornen-2-one and 7-oxanorbornen-2-one has been studied by1H and13C n.m.r. spectroscopy. Elucidation of the reason for the preference for the £-isomer in both cases has been attempted by molecular mechanics calculations. This preference may be justified by A1,3 allylic interactions. © 1988, The Royal Society of Chemistry. All rights reserved.

Original language	English
Pages (from-to)	865-868
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	6
DOIs	https://doi.org/10.1039/P29880000865
Publication status	Published - 1 Jan 1988

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title = "Role of the a1, 3 allylic interaction on the stereochemistry of formation of schiff{\textquoteright}s bases derived from bicyclo[2.2.1]hept-5-en-2-one and 7-oxabicyclo[2.2.1]hept-5-en-2-one",

abstract = "The stereochemistry of formation of Schiff′s bases de rived from norbornen-2-one and 7-oxanorbornen-2-one has been studied by1H and13C n.m.r. spectroscopy. Elucidation of the reason for the preference for the £-isomer in both cases has been attempted by molecular mechanics calculations. This preference may be justified by A1,3 allylic interactions. {\textcopyright} 1988, The Royal Society of Chemistry. All rights reserved.",

author = "Od{\'o}n Arjona and Araceli Mallo and Cristina Manzano and Joaqu{\'i}n Plumet and Juan Galbis and Carlos Jaime",

year = "1988",

month = jan,

day = "1",

doi = "10.1039/P29880000865",

language = "English",

pages = "865--868",

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Role of the a^{1, 3} allylic interaction on the stereochemistry of formation of schiff’s bases derived from bicyclo[2.2.1]hept-5-en-2-one and 7-oxabicyclo[2.2.1]hept-5-en-2-one. / Arjona, Odón; Mallo, Araceli; Manzano, Cristina et al.

In: Journal of the Chemical Society, Perkin Transactions 2, No. 6, 01.01.1988, p. 865-868.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Role of the a1, 3 allylic interaction on the stereochemistry of formation of schiff’s bases derived from bicyclo[2.2.1]hept-5-en-2-one and 7-oxabicyclo[2.2.1]hept-5-en-2-one

AU - Arjona, Odón

AU - Mallo, Araceli

AU - Manzano, Cristina

AU - Plumet, Joaquín

AU - Galbis, Juan

AU - Jaime, Carlos

PY - 1988/1/1

Y1 - 1988/1/1

N2 - The stereochemistry of formation of Schiff′s bases de rived from norbornen-2-one and 7-oxanorbornen-2-one has been studied by1H and13C n.m.r. spectroscopy. Elucidation of the reason for the preference for the £-isomer in both cases has been attempted by molecular mechanics calculations. This preference may be justified by A1,3 allylic interactions. © 1988, The Royal Society of Chemistry. All rights reserved.

AB - The stereochemistry of formation of Schiff′s bases de rived from norbornen-2-one and 7-oxanorbornen-2-one has been studied by1H and13C n.m.r. spectroscopy. Elucidation of the reason for the preference for the £-isomer in both cases has been attempted by molecular mechanics calculations. This preference may be justified by A1,3 allylic interactions. © 1988, The Royal Society of Chemistry. All rights reserved.

U2 - 10.1039/P29880000865

DO - 10.1039/P29880000865

M3 - Article

SP - 865

EP - 868

IS - 6

ER -

Role of the a1, 3 allylic interaction on the stereochemistry of formation of schiff’s bases derived from bicyclo[2.2.1]hept-5-en-2-one and 7-oxabicyclo[2.2.1]hept-5-en-2-one

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Role of the a^{1, 3} allylic interaction on the stereochemistry of formation of schiff’s bases derived from bicyclo[2.2.1]hept-5-en-2-one and 7-oxabicyclo[2.2.1]hept-5-en-2-one