Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Z. Freixa, J. C. Bayón

Research output: Contribution to journalArticleResearchpeer-review

17 Citations (Scopus)

Abstract

A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.
Original languageEnglish
Pages (from-to)2067-2068
JournalJournal of the Chemical Society, Dalton Transactions
Issue number14
DOIs
Publication statusPublished - 9 Aug 2001

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