Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Z. Freixa; J. C. Bayón

doi:10.1039/b105208j

Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Z. Freixa, J. C. Bayón

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.

Original language	English
Pages (from-to)	2067-2068
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/b105208j
Publication status	Published - 9 Aug 2001

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title = "Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring",

abstract = "A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.",

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N2 - A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.

AB - A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.

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DO - 10.1039/b105208j

M3 - Article

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JF - Journal of the Chemical Society, Dalton Transactions

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ER -

Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Abstract

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