Abstract
Some regiosomers formed by palladium(0)‐catalysed allylation of several ambident heterocyclic nucleophiles, among others, were easily distinguished in very short spectrometer times by selective polarization transfer via DEPT from well resolved protons to long‐range coupled carbons using the SDEPT‐1D experiment. This pulse sequence was also analysed in terms of the product operator formalism. These structural elucidations can provide useful information about the regioselectivity in these reactions. Copyright © 1994 John Wiley & Sons Limited
Original language | English |
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Pages (from-to) | 343-347 |
Journal | Magnetic Resonance in Chemistry |
Volume | 32 |
Issue number | 6 |
DOIs | |
Publication status | Published - 1 Jan 1994 |
Keywords
- Delective allylation
- Long‐range H C couplings 1 13
- Selective DEPT