Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The S<inf>RN</inf>2 hypothesis revisited

Jorge Marquet; Ziqi Jiang; Iluminada Gallardo; Anna Batlle; Eduard Cayón

doi:10.1016/S0040-4039(00)73566-0

Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The S<inf>RN</inf>2 hypothesis revisited

Jorge Marquet, Ziqi Jiang, Iluminada Gallardo, Anna Batlle, Eduard Cayón

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

25 Citations (Scopus)

Abstract

The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. © 1993.

Original language	English
Pages (from-to)	2801-2804
Journal	Tetrahedron Letters
Volume	34
Issue number	17
DOIs	https://doi.org/10.1016/S0040-4039(00)73566-0
Publication status	Published - 23 Apr 1993

Access to Document

10.1016/S0040-4039(00)73566-0

Cite this

@article{52f4f5520bb0454ab1b2fcfb652fc867,

title = "Reductively activated {"}polar{"} nucleophilic aromatic substitution of pentafluoronitrobenzene. The SRN2 hypothesis revisited",

abstract = "The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. {\textcopyright} 1993.",

author = "Jorge Marquet and Ziqi Jiang and Iluminada Gallardo and Anna Batlle and Eduard Cay{\'o}n",

year = "1993",

month = apr,

day = "23",

doi = "10.1016/S0040-4039(00)73566-0",

language = "English",

volume = "34",

pages = "2801--2804",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "17",

}

TY - JOUR

T1 - Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The SRN2 hypothesis revisited

AU - Marquet, Jorge

AU - Jiang, Ziqi

AU - Gallardo, Iluminada

AU - Batlle, Anna

AU - Cayón, Eduard

PY - 1993/4/23

Y1 - 1993/4/23

N2 - The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. © 1993.

AB - The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. © 1993.

UR - https://www.scopus.com/pages/publications/0027158864

U2 - 10.1016/S0040-4039(00)73566-0

DO - 10.1016/S0040-4039(00)73566-0

M3 - Article

SN - 0040-4039

VL - 34

SP - 2801

EP - 2804

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 17

ER -

Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The S<inf>RN</inf>2 hypothesis revisited

Abstract

Access to Document

Other files and links

Fingerprint

Cite this