Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The S<inf>RN</inf>2 hypothesis revisited

Jorge Marquet, Ziqi Jiang, Iluminada Gallardo, Anna Batlle, Eduard Cayón

Research output: Contribution to journalArticleResearchpeer-review

21 Citations (Scopus)

Abstract

The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. © 1993.
Original languageEnglish
Pages (from-to)2801-2804
JournalTetrahedron Letters
Volume34
Issue number17
DOIs
Publication statusPublished - 23 Apr 1993

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