TY - JOUR
T1 - Reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-nido-undecaborate. Molecular structure of [7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate]bis(triphenylphosphine)rhodium(I)
AU - Teixidor, F.
AU - Rius, J.
AU - Miravitlles, C.
AU - Viñas, C.
AU - Escriche, Ll
AU - Sanchez, E.
AU - Casabó, J.
PY - 1990/10/1
Y1 - 1990/10/1
N2 - The reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate is reported. It reacts easily with salts of transition metals, replaces phosphines in complexes where these are ligands, and stabilizes low oxidation states. The molecular structure of 1,4-dithiabutane-7′,8′-dicarbaundecaborate(12)bis(triphenylphosphine)rhodium(I) has been resolved. The compound crystallizes in space group P1 with 2 formula units per cell. The cell dimensions are a=10.165(2), b=14.665(3), c=14.951(3) Å with α=81.21(4), β=87.68(4) and γ= 72.20°. © 1990.
AB - The reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate is reported. It reacts easily with salts of transition metals, replaces phosphines in complexes where these are ligands, and stabilizes low oxidation states. The molecular structure of 1,4-dithiabutane-7′,8′-dicarbaundecaborate(12)bis(triphenylphosphine)rhodium(I) has been resolved. The compound crystallizes in space group P1 with 2 formula units per cell. The cell dimensions are a=10.165(2), b=14.665(3), c=14.951(3) Å with α=81.21(4), β=87.68(4) and γ= 72.20°. © 1990.
U2 - 10.1016/S0020-1693(00)85092-6
DO - 10.1016/S0020-1693(00)85092-6
M3 - Article
VL - 176
SP - 61
EP - 65
IS - 1
ER -