Reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-nido-undecaborate. Molecular structure of [7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate]bis(triphenylphosphine)rhodium(I)

F. Teixidor; J. Rius; C. Miravitlles; C. Viñas; Ll Escriche; E. Sanchez; J. Casabó

doi:10.1016/S0020-1693(00)85092-6

Reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-nido-undecaborate. Molecular structure of [7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate]bis(triphenylphosphine)rhodium(I)

F. Teixidor, J. Rius, C. Miravitlles, C. Viñas, Ll Escriche, E. Sanchez, J. Casabó

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

20 Citations (Scopus)

Abstract

The reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate is reported. It reacts easily with salts of transition metals, replaces phosphines in complexes where these are ligands, and stabilizes low oxidation states. The molecular structure of 1,4-dithiabutane-7′,8′-dicarbaundecaborate(12)bis(triphenylphosphine)rhodium(I) has been resolved. The compound crystallizes in space group P1 with 2 formula units per cell. The cell dimensions are a=10.165(2), b=14.665(3), c=14.951(3) Å with α=81.21(4), β=87.68(4) and γ= 72.20°. © 1990.

Original language	English
Pages (from-to)	61-65
Journal	Inorg. Chim. Acta
Volume	176
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)85092-6
Publication status	Published - 1 Oct 1990

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Teixidor, F., Rius, J., Miravitlles, C., Viñas, C., Escriche, L., Sanchez, E., & Casabó, J. (1990). Reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-nido-undecaborate. Molecular structure of [7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate]bis(triphenylphosphine)rhodium(I). Inorg. Chim. Acta, 176(1), 61-65. https://doi.org/10.1016/S0020-1693(00)85092-6

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title = "Reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-nido-undecaborate. Molecular structure of [7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate]bis(triphenylphosphine)rhodium(I)",

abstract = "The reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate is reported. It reacts easily with salts of transition metals, replaces phosphines in complexes where these are ligands, and stabilizes low oxidation states. The molecular structure of 1,4-dithiabutane-7′,8′-dicarbaundecaborate(12)bis(triphenylphosphine)rhodium(I) has been resolved. The compound crystallizes in space group P1 with 2 formula units per cell. The cell dimensions are a=10.165(2), b=14.665(3), c=14.951(3) {\AA} with α=81.21(4), β=87.68(4) and γ= 72.20°. {\textcopyright} 1990.",

author = "F. Teixidor and J. Rius and C. Miravitlles and C. Vi{\~n}as and Ll Escriche and E. Sanchez and J. Casab{\'o}",

year = "1990",

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doi = "10.1016/S0020-1693(00)85092-6",

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Teixidor, F, Rius, J, Miravitlles, C, Viñas, C, Escriche, L, Sanchez, E & Casabó, J 1990, 'Reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-nido-undecaborate. Molecular structure of [7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate]bis(triphenylphosphine)rhodium(I)', Inorg. Chim. Acta, vol. 176, no. 1, pp. 61-65. https://doi.org/10.1016/S0020-1693(00)85092-6

Reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-nido-undecaborate. Molecular structure of [7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate]bis(triphenylphosphine)rhodium(I). / Teixidor, F.; Rius, J.; Miravitlles, C. et al.

In: Inorg. Chim. Acta, Vol. 176, No. 1, 01.10.1990, p. 61-65.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-nido-undecaborate. Molecular structure of [7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate]bis(triphenylphosphine)rhodium(I)

AU - Teixidor, F.

AU - Rius, J.

AU - Miravitlles, C.

AU - Viñas, C.

AU - Escriche, Ll

AU - Sanchez, E.

AU - Casabó, J.

PY - 1990/10/1

Y1 - 1990/10/1

N2 - The reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate is reported. It reacts easily with salts of transition metals, replaces phosphines in complexes where these are ligands, and stabilizes low oxidation states. The molecular structure of 1,4-dithiabutane-7′,8′-dicarbaundecaborate(12)bis(triphenylphosphine)rhodium(I) has been resolved. The compound crystallizes in space group P1 with 2 formula units per cell. The cell dimensions are a=10.165(2), b=14.665(3), c=14.951(3) Å with α=81.21(4), β=87.68(4) and γ= 72.20°. © 1990.

AB - The reactivity of the anion 7,8-(ethane-1′,2′-dithiolato-SS′)-dicarba-nido-undecaborate is reported. It reacts easily with salts of transition metals, replaces phosphines in complexes where these are ligands, and stabilizes low oxidation states. The molecular structure of 1,4-dithiabutane-7′,8′-dicarbaundecaborate(12)bis(triphenylphosphine)rhodium(I) has been resolved. The compound crystallizes in space group P1 with 2 formula units per cell. The cell dimensions are a=10.165(2), b=14.665(3), c=14.951(3) Å with α=81.21(4), β=87.68(4) and γ= 72.20°. © 1990.

U2 - 10.1016/S0020-1693(00)85092-6

DO - 10.1016/S0020-1693(00)85092-6

M3 - Article

VL - 176

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EP - 65

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

IS - 1

ER -