Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)

Antonio de León; Josefina Pons; Jordi García-Antón; Xavier Solans; Mercè Font-Bardía; Josep Ros

doi:10.1016/j.ica.2009.04.045

Reactivity of [PdCl(bdtp)](BF₄) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh₃)](BF₄)₂ (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)

Antonio de León, Josefina Pons, Jordi García-Antón, Xavier Solans, Mercè Font-Bardía, Josep Ros

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

Complex [PdCl(bdtp)](BF4), in presence of AgBF4 or NaBF4, reacts with pyridine (py), triphenylphosphine (PPh3), cyanide (CN-), thiocyanate (SCN-) or azide (N3-) ligands, leading to the formation of the following complexes: [Pd(bdtp)(py)](BF4)2 [1](BF4)2, [Pd(bdtp)(PPh3)](BF4)2 [2](BF4)2, [Pd(CN)(bdtp)](BF4) [3](BF4), [Pd(SCN)(bdtp)](BF4) [4](BF4) and [Pd(N3)(bdtp)](BF4) [5](BF4). These complexes were characterised by elemental analyses, mass spectrometry, conductivity measurements, infrared and NMR spectroscopies. The crystal structure of [2](BF4)2 was determined by single-crystal X-ray diffraction methods. The metal atom is coordinated by two azine nitrogen atoms, and one sulfur atom of the thioether-pyrazole ligand and one triphenylphosphine in a distorted square-planar geometry. © 2009 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	3801-3806
Journal	Inorganica Chimica Acta
Volume	362
Issue number	10
DOIs	https://doi.org/10.1016/j.ica.2009.04.045
Publication status	Published - 1 Aug 2009

Keywords

Crystal structure
N,S ligand
Palladium

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@article{2450a02d1e434e149a8a9e4cc276154f,

title = "Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)",

abstract = "Complex [PdCl(bdtp)](BF4), in presence of AgBF4 or NaBF4, reacts with pyridine (py), triphenylphosphine (PPh3), cyanide (CN-), thiocyanate (SCN-) or azide (N3-) ligands, leading to the formation of the following complexes: [Pd(bdtp)(py)](BF4)2 [1](BF4)2, [Pd(bdtp)(PPh3)](BF4)2 [2](BF4)2, [Pd(CN)(bdtp)](BF4) [3](BF4), [Pd(SCN)(bdtp)](BF4) [4](BF4) and [Pd(N3)(bdtp)](BF4) [5](BF4). These complexes were characterised by elemental analyses, mass spectrometry, conductivity measurements, infrared and NMR spectroscopies. The crystal structure of [2](BF4)2 was determined by single-crystal X-ray diffraction methods. The metal atom is coordinated by two azine nitrogen atoms, and one sulfur atom of the thioether-pyrazole ligand and one triphenylphosphine in a distorted square-planar geometry. {\textcopyright} 2009 Elsevier B.V. All rights reserved.",

keywords = "Crystal structure, N,S ligand, Palladium",

author = "{de Le{\'o}n}, Antonio and Josefina Pons and Jordi Garc{\'i}a-Ant{\'o}n and Xavier Solans and Merc{\`e} Font-Bard{\'i}a and Josep Ros",

year = "2009",

month = aug,

day = "1",

doi = "10.1016/j.ica.2009.04.045",

language = "English",

volume = "362",

pages = "3801--3806",

number = "10",

}

Reactivity of [PdCl(bdtp)](BF₄) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh₃)](BF₄)₂ (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane). / de León, Antonio; Pons, Josefina ; García-Antón, Jordi ; Solans, Xavier; Font-Bardía, Mercè; Ros, Josep.

In: Inorganica Chimica Acta, Vol. 362, No. 10, 01.08.2009, p. 3801-3806.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Reactivity of [PdCl(bdtp)](BF4) with monodentate neutral and anionic ligands. Structure of [Pd(bdtp)(PPh3)](BF4)2 (bdtp = 1,5-bis(3,5-dimethyl-1-pyrazolyl)-3-thiapentane)

AU - de León, Antonio

AU - Pons, Josefina

AU - García-Antón, Jordi

AU - Solans, Xavier

AU - Font-Bardía, Mercè

AU - Ros, Josep

PY - 2009/8/1

Y1 - 2009/8/1

N2 - Complex [PdCl(bdtp)](BF4), in presence of AgBF4 or NaBF4, reacts with pyridine (py), triphenylphosphine (PPh3), cyanide (CN-), thiocyanate (SCN-) or azide (N3-) ligands, leading to the formation of the following complexes: [Pd(bdtp)(py)](BF4)2 [1](BF4)2, [Pd(bdtp)(PPh3)](BF4)2 [2](BF4)2, [Pd(CN)(bdtp)](BF4) [3](BF4), [Pd(SCN)(bdtp)](BF4) [4](BF4) and [Pd(N3)(bdtp)](BF4) [5](BF4). These complexes were characterised by elemental analyses, mass spectrometry, conductivity measurements, infrared and NMR spectroscopies. The crystal structure of [2](BF4)2 was determined by single-crystal X-ray diffraction methods. The metal atom is coordinated by two azine nitrogen atoms, and one sulfur atom of the thioether-pyrazole ligand and one triphenylphosphine in a distorted square-planar geometry. © 2009 Elsevier B.V. All rights reserved.

AB - Complex [PdCl(bdtp)](BF4), in presence of AgBF4 or NaBF4, reacts with pyridine (py), triphenylphosphine (PPh3), cyanide (CN-), thiocyanate (SCN-) or azide (N3-) ligands, leading to the formation of the following complexes: [Pd(bdtp)(py)](BF4)2 [1](BF4)2, [Pd(bdtp)(PPh3)](BF4)2 [2](BF4)2, [Pd(CN)(bdtp)](BF4) [3](BF4), [Pd(SCN)(bdtp)](BF4) [4](BF4) and [Pd(N3)(bdtp)](BF4) [5](BF4). These complexes were characterised by elemental analyses, mass spectrometry, conductivity measurements, infrared and NMR spectroscopies. The crystal structure of [2](BF4)2 was determined by single-crystal X-ray diffraction methods. The metal atom is coordinated by two azine nitrogen atoms, and one sulfur atom of the thioether-pyrazole ligand and one triphenylphosphine in a distorted square-planar geometry. © 2009 Elsevier B.V. All rights reserved.

KW - Crystal structure

KW - N,S ligand

KW - Palladium

U2 - 10.1016/j.ica.2009.04.045

DO - 10.1016/j.ica.2009.04.045

M3 - Article

VL - 362

SP - 3801

EP - 3806

IS - 10

ER -