Reactions of Ru(HCCHR)Cl(CO)(PPh <inf>3</inf> ) <inf>2</inf> with functionalized carboxylates. Crystal structure of Ru(HCCHPh)(O <inf>2</inf> CCHCHCHCHCH <inf>3</inf> )(CO)(PPh <inf>3</inf> ) <inf>2</inf>

M. El Guaouzi; J. Ros; X. Solans; M. Font-Bardía

doi:10.1016/0020-1693(94)04319-Q

Reactions of Ru(HCCHR)Cl(CO)(PPh <inf>3</inf> ) <inf>2</inf> with functionalized carboxylates. Crystal structure of Ru(HCCHPh)(O <inf>2</inf> CCHCHCHCHCH <inf>3</inf> )(CO)(PPh <inf>3</inf> ) <inf>2</inf>

M. El Guaouzi, J. Ros, X. Solans, M. Font-Bardía

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

12 Citations (Scopus)

Abstract

The coordinatively unsaturated 16-electron complexes Ru(HCCHR)Cl(CO)(PPh 3 ) 2 (R t Bu and Ph) react with the sodium salts of functionalized carboxylates NaO 2 CR′ (R′MeCHCHCHCH, CH 2 CHCH 2 , PhCC and MeCC) to give saturated complexes of formulae Ru(HCCHR)(O 2 CR′)(CO)(PPh 3 ) 2 , where the carboxylate group acts as an η 2 -coordinated ligand. The structure of the complex Ru(HCCHPh)(O 2 CCHCHCHCHCH 3 )(CO)(PPh 3 ) 2 has been determined by X-ray diffraction. Crystals are monoclinic, space group P2 1 /n with dimensions of the unit cell of a = 12.191(3), b = 18.596(4), c = 20.001(4) A ̊, β = 107.23(3)° and D x = 1.331 g cm -3 for Z = 4. All the complexes have been identified by IR, 1 H NMR and 31 P NMR spectroscopies, and from their C and H elemental analyses. © 1995.

Original language	English
Pages (from-to)	181-186
Journal	Inorganica Chimica Acta
Volume	231
Issue number	1-2
DOIs	https://doi.org/10.1016/0020-1693(94)04319-Q
Publication status	Published - 15 Mar 1995

Keywords

Carboxylate complexes
Crystal structures
Olefin Complexes
Ruthenium complexes

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@article{52a6aee71d074a5bbbc031b2bf81a652,

title = "Reactions of Ru(HCCHR)Cl(CO)(PPh 3 ) 2 with functionalized carboxylates. Crystal structure of Ru(HCCHPh)(O 2 CCHCHCHCHCH 3 )(CO)(PPh 3 ) 2",

abstract = "The coordinatively unsaturated 16-electron complexes Ru(HCCHR)Cl(CO)(PPh 3 ) 2 (R t Bu and Ph) react with the sodium salts of functionalized carboxylates NaO 2 CR′ (R′MeCHCHCHCH, CH 2 CHCH 2 , PhCC and MeCC) to give saturated complexes of formulae Ru(HCCHR)(O 2 CR′)(CO)(PPh 3 ) 2 , where the carboxylate group acts as an η 2 -coordinated ligand. The structure of the complex Ru(HCCHPh)(O 2 CCHCHCHCHCH 3 )(CO)(PPh 3 ) 2 has been determined by X-ray diffraction. Crystals are monoclinic, space group P2 1 /n with dimensions of the unit cell of a = 12.191(3), b = 18.596(4), c = 20.001(4) A ̊, β = 107.23(3)° and D x = 1.331 g cm -3 for Z = 4. All the complexes have been identified by IR, 1 H NMR and 31 P NMR spectroscopies, and from their C and H elemental analyses. {\textcopyright} 1995.",

keywords = "Carboxylate complexes, Crystal structures, Olefin Complexes, Ruthenium complexes",

author = "Guaouzi, {M. El} and J. Ros and X. Solans and M. Font-Bard{\'i}a",

year = "1995",

month = mar,

day = "15",

doi = "10.1016/0020-1693(94)04319-Q",

language = "English",

volume = "231",

pages = "181--186",

number = "1-2",

}

Reactions of Ru(HCCHR)Cl(CO)(PPh <inf>3</inf> ) <inf>2</inf> with functionalized carboxylates. Crystal structure of Ru(HCCHPh)(O <inf>2</inf> CCHCHCHCHCH <inf>3</inf> )(CO)(PPh <inf>3</inf> ) <inf>2</inf> / Guaouzi, M. El; Ros, J.; Solans, X.; Font-Bardía, M.

In: Inorganica Chimica Acta, Vol. 231, No. 1-2, 15.03.1995, p. 181-186.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Reactions of Ru(HCCHR)Cl(CO)(PPh 3 ) 2 with functionalized carboxylates. Crystal structure of Ru(HCCHPh)(O 2 CCHCHCHCHCH 3 )(CO)(PPh 3 ) 2

AU - Guaouzi, M. El

AU - Ros, J.

AU - Solans, X.

AU - Font-Bardía, M.

PY - 1995/3/15

Y1 - 1995/3/15

N2 - The coordinatively unsaturated 16-electron complexes Ru(HCCHR)Cl(CO)(PPh 3 ) 2 (R t Bu and Ph) react with the sodium salts of functionalized carboxylates NaO 2 CR′ (R′MeCHCHCHCH, CH 2 CHCH 2 , PhCC and MeCC) to give saturated complexes of formulae Ru(HCCHR)(O 2 CR′)(CO)(PPh 3 ) 2 , where the carboxylate group acts as an η 2 -coordinated ligand. The structure of the complex Ru(HCCHPh)(O 2 CCHCHCHCHCH 3 )(CO)(PPh 3 ) 2 has been determined by X-ray diffraction. Crystals are monoclinic, space group P2 1 /n with dimensions of the unit cell of a = 12.191(3), b = 18.596(4), c = 20.001(4) A ̊, β = 107.23(3)° and D x = 1.331 g cm -3 for Z = 4. All the complexes have been identified by IR, 1 H NMR and 31 P NMR spectroscopies, and from their C and H elemental analyses. © 1995.

AB - The coordinatively unsaturated 16-electron complexes Ru(HCCHR)Cl(CO)(PPh 3 ) 2 (R t Bu and Ph) react with the sodium salts of functionalized carboxylates NaO 2 CR′ (R′MeCHCHCHCH, CH 2 CHCH 2 , PhCC and MeCC) to give saturated complexes of formulae Ru(HCCHR)(O 2 CR′)(CO)(PPh 3 ) 2 , where the carboxylate group acts as an η 2 -coordinated ligand. The structure of the complex Ru(HCCHPh)(O 2 CCHCHCHCHCH 3 )(CO)(PPh 3 ) 2 has been determined by X-ray diffraction. Crystals are monoclinic, space group P2 1 /n with dimensions of the unit cell of a = 12.191(3), b = 18.596(4), c = 20.001(4) A ̊, β = 107.23(3)° and D x = 1.331 g cm -3 for Z = 4. All the complexes have been identified by IR, 1 H NMR and 31 P NMR spectroscopies, and from their C and H elemental analyses. © 1995.

KW - Carboxylate complexes

KW - Crystal structures

KW - Olefin Complexes

KW - Ruthenium complexes

U2 - 10.1016/0020-1693(94)04319-Q

DO - 10.1016/0020-1693(94)04319-Q

M3 - Article

VL - 231

SP - 181

EP - 186

IS - 1-2

ER -