Reactions of Ru(CO)Cl(RCCHR′)(PPh<inf>3</inf>)<inf>2</inf> with carboxylates. The crystal structure of Ru(O<inf>2</inf>CMe)(CO)(HCCHPh)(PPh<inf>3</inf>)<inf>2</inf>

M. Rosario Torres; Aurea Perales; Hassane Loumrhari; Josep Ros

doi:10.1016/0022-328X(90)85009-N

Reactions of Ru(CO)Cl(RCCHR′)(PPh<inf>3</inf>)<inf>2</inf> with carboxylates. The crystal structure of Ru(O<inf>2</inf>CMe)(CO)(HCCHPh)(PPh<inf>3</inf>)<inf>2</inf>

M. Rosario Torres, Aurea Perales, Hassane Loumrhari, Josep Ros

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

42 Citations (Scopus)

Abstract

The 16-electron complexes Ru(CO)Cl(RCCHR′)(PPh3)2 (R = H, R′ = CMe3, SiMe3, Ph, CO2Me and CO2Et; R = R′ = H, Me, Ph and CO2Me react readily with carboxylates to give the saturated complexes Ru(O2CR″)(CO)(RCCHR′)(PPh3)2 (R″ = Me and Et). The crystal structure of the complex Ru(O2CMe)(CO)(HCCHPh)(PPh3)2 has been determined, and reveals an octahedral geometry for the ruthenium atom bearing two phosphines in a trans-disposition and η2-acetate, CO and η1-phenylethenyl ligands. © 1990.

Original language	English
Pages (from-to)	379-386
Journal	Journal of Organometallic Chemistry
Volume	385
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(90)85009-N
Publication status	Published - 27 Mar 1990

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@article{f85f47d2fdf446d5af21fca2996e0511,

title = "Reactions of Ru(CO)Cl(RCCHR′)(PPh3)2 with carboxylates. The crystal structure of Ru(O2CMe)(CO)(HCCHPh)(PPh3)2",

abstract = "The 16-electron complexes Ru(CO)Cl(RCCHR′)(PPh3)2 (R = H, R′ = CMe3, SiMe3, Ph, CO2Me and CO2Et; R = R′ = H, Me, Ph and CO2Me react readily with carboxylates to give the saturated complexes Ru(O2CR″)(CO)(RCCHR′)(PPh3)2 (R″ = Me and Et). The crystal structure of the complex Ru(O2CMe)(CO)(HCCHPh)(PPh3)2 has been determined, and reveals an octahedral geometry for the ruthenium atom bearing two phosphines in a trans-disposition and η2-acetate, CO and η1-phenylethenyl ligands. {\textcopyright} 1990.",

author = "Torres, {M. Rosario} and Aurea Perales and Hassane Loumrhari and Josep Ros",

year = "1990",

month = mar,

day = "27",

doi = "10.1016/0022-328X(90)85009-N",

language = "English",

volume = "385",

pages = "379--386",

number = "3",

}

Reactions of Ru(CO)Cl(RCCHR′)(PPh<inf>3</inf>)<inf>2</inf> with carboxylates. The crystal structure of Ru(O<inf>2</inf>CMe)(CO)(HCCHPh)(PPh<inf>3</inf>)<inf>2</inf> / Torres, M. Rosario; Perales, Aurea; Loumrhari, Hassane; Ros, Josep.

In: Journal of Organometallic Chemistry, Vol. 385, No. 3, 27.03.1990, p. 379-386.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Reactions of Ru(CO)Cl(RCCHR′)(PPh3)2 with carboxylates. The crystal structure of Ru(O2CMe)(CO)(HCCHPh)(PPh3)2

AU - Torres, M. Rosario

AU - Perales, Aurea

AU - Loumrhari, Hassane

AU - Ros, Josep

PY - 1990/3/27

Y1 - 1990/3/27

N2 - The 16-electron complexes Ru(CO)Cl(RCCHR′)(PPh3)2 (R = H, R′ = CMe3, SiMe3, Ph, CO2Me and CO2Et; R = R′ = H, Me, Ph and CO2Me react readily with carboxylates to give the saturated complexes Ru(O2CR″)(CO)(RCCHR′)(PPh3)2 (R″ = Me and Et). The crystal structure of the complex Ru(O2CMe)(CO)(HCCHPh)(PPh3)2 has been determined, and reveals an octahedral geometry for the ruthenium atom bearing two phosphines in a trans-disposition and η2-acetate, CO and η1-phenylethenyl ligands. © 1990.

AB - The 16-electron complexes Ru(CO)Cl(RCCHR′)(PPh3)2 (R = H, R′ = CMe3, SiMe3, Ph, CO2Me and CO2Et; R = R′ = H, Me, Ph and CO2Me react readily with carboxylates to give the saturated complexes Ru(O2CR″)(CO)(RCCHR′)(PPh3)2 (R″ = Me and Et). The crystal structure of the complex Ru(O2CMe)(CO)(HCCHPh)(PPh3)2 has been determined, and reveals an octahedral geometry for the ruthenium atom bearing two phosphines in a trans-disposition and η2-acetate, CO and η1-phenylethenyl ligands. © 1990.

U2 - 10.1016/0022-328X(90)85009-N

DO - 10.1016/0022-328X(90)85009-N

M3 - Article

VL - 385

SP - 379

EP - 386

IS - 3

ER -