Reactions of dinuclear carboxylate ruthenium (I) complexes with alcohols. the unexpected oxidation of primary alcohols to carboxylic ligands

Josep Soler; Isabel Moldes; Esther De La Encarnación; Josep Ros

doi:10.1016/S0022-328X(98)01131-0

Reactions of dinuclear carboxylate ruthenium (I) complexes with alcohols. the unexpected oxidation of primary alcohols to carboxylic ligands

Josep Soler, Isabel Moldes, Esther De La Encarnación, Josep Ros

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

3 Citations (Scopus)

Abstract

The dinuclear ruthenium (I) complexes [Ru2(HCO2)2(CO)4(PPh 3)2] react with primary alcohols R′CH2OH in refluxing toluene, giving rise to [Ru2(R′CO2)2(CO)4(PPh 3)2] compounds. Other carboxylate bridging complexes react with alcohols R″OH to give very unstable alkoxide compounds [Ru2(R″O)2(CO)4(PPh3) 2]. © 1999 Elsevier Science S.A.

Original language	English
Pages (from-to)	108-109
Journal	Journal of Organometallic Chemistry
Volume	580
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(98)01131-0
Publication status	Published - 15 May 1999

Keywords

Alkoxide
Carboxylate
Formate
Ruthenium

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10.1016/S0022-328X(98)01131-0

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title = "Reactions of dinuclear carboxylate ruthenium (I) complexes with alcohols. the unexpected oxidation of primary alcohols to carboxylic ligands",

abstract = "The dinuclear ruthenium (I) complexes [Ru2(HCO2)2(CO)4(PPh 3)2] react with primary alcohols R′CH2OH in refluxing toluene, giving rise to [Ru2(R′CO2)2(CO)4(PPh 3)2] compounds. Other carboxylate bridging complexes react with alcohols R″OH to give very unstable alkoxide compounds [Ru2(R″O)2(CO)4(PPh3) 2]. {\textcopyright} 1999 Elsevier Science S.A.",

keywords = "Alkoxide, Carboxylate, Formate, Ruthenium",

author = "Josep Soler and Isabel Moldes and {De La Encarnaci{\'o}n}, Esther and Josep Ros",

year = "1999",

month = may,

day = "15",

doi = "10.1016/S0022-328X(98)01131-0",

language = "English",

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Reactions of dinuclear carboxylate ruthenium (I) complexes with alcohols. the unexpected oxidation of primary alcohols to carboxylic ligands. / Soler, Josep; Moldes, Isabel; De La Encarnación, Esther; Ros, Josep.

In: Journal of Organometallic Chemistry, Vol. 580, No. 1, 15.05.1999, p. 108-109.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Reactions of dinuclear carboxylate ruthenium (I) complexes with alcohols. the unexpected oxidation of primary alcohols to carboxylic ligands

AU - Soler, Josep

AU - Moldes, Isabel

AU - De La Encarnación, Esther

AU - Ros, Josep

PY - 1999/5/15

Y1 - 1999/5/15

N2 - The dinuclear ruthenium (I) complexes [Ru2(HCO2)2(CO)4(PPh 3)2] react with primary alcohols R′CH2OH in refluxing toluene, giving rise to [Ru2(R′CO2)2(CO)4(PPh 3)2] compounds. Other carboxylate bridging complexes react with alcohols R″OH to give very unstable alkoxide compounds [Ru2(R″O)2(CO)4(PPh3) 2]. © 1999 Elsevier Science S.A.

AB - The dinuclear ruthenium (I) complexes [Ru2(HCO2)2(CO)4(PPh 3)2] react with primary alcohols R′CH2OH in refluxing toluene, giving rise to [Ru2(R′CO2)2(CO)4(PPh 3)2] compounds. Other carboxylate bridging complexes react with alcohols R″OH to give very unstable alkoxide compounds [Ru2(R″O)2(CO)4(PPh3) 2]. © 1999 Elsevier Science S.A.

KW - Alkoxide

KW - Carboxylate

KW - Formate

KW - Ruthenium

U2 - 10.1016/S0022-328X(98)01131-0

DO - 10.1016/S0022-328X(98)01131-0

M3 - Article

VL - 580

SP - 108

EP - 109

IS - 1

ER -