Reactions of acylferrate anion [CH3COFe(CO)4]- with methyl methyl iodide and acetylenes. Synthesis of mono- and dinuclear alkenyl ketone iron complexes. X-ray structure of [NEt4][IFe(CO)3(COCPh)2)]

Abdelhay Elarraoui; Josep Ros; Ramón Yáñez; Xavier Solans; Mercè Font-Bardia

doi:10.1016/S0022-328X(01)01177-9

Reactions of acylferrate anion [CH₃COFe(CO)₄]^- with methyl methyl iodide and acetylenes. Synthesis of mono- and dinuclear alkenyl ketone iron complexes. X-ray structure of [NEt₄][IFe(CO)₃(COCPh)₂)]

Abdelhay Elarraoui, Josep Ros, Ramón Yáñez, Xavier Solans, Mercè Font-Bardia

Department of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

15 Citations (Scopus)

Abstract

Collman's reagent [NEt4][CH3COFe(CO)4] (1) reacts with a half equivalent of methyl iodide and diphenylacetylene in acetone at 25 °C for 10 min to give [NEt4][Fe2(CO)6(μ2-CPhCPh COCH3)] (2). When the reaction of [NEt4][CH3COFe(CO)4] (1) was carried out with an excess of methyl iodide a mixture of [NEt4][IFe(CO)3(C(O)CPh)2] (3) and Fe2(CO)6μ-CPhCPhCCH3 (OCH3) (4) complexes were obtained. Complex 3 was characterized by X-ray analyses. © 2002 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	107-112
Journal	Journal of Organometallic Chemistry
Volume	642
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(01)01177-9
Publication status	Published - 1 Jan 2002

Keywords

Alkyne
Carbonyl
Dinuclear
Iron

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Elarraoui, A., Ros, J., Yáñez, R., Solans, X., & Font-Bardia, M. (2002). Reactions of acylferrate anion [CH₃COFe(CO)₄]^- with methyl methyl iodide and acetylenes. Synthesis of mono- and dinuclear alkenyl ketone iron complexes. X-ray structure of [NEt₄][IFe(CO)₃(COCPh)₂)]. Journal of Organometallic Chemistry, 642(1-2), 107-112. https://doi.org/10.1016/S0022-328X(01)01177-9

Elarraoui, Abdelhay ; Ros, Josep ; Yáñez, Ramón ; Solans, Xavier ; Font-Bardia, Mercè. / Reactions of acylferrate anion [CH₃COFe(CO)₄]^- with methyl methyl iodide and acetylenes. Synthesis of mono- and dinuclear alkenyl ketone iron complexes. X-ray structure of [NEt₄][IFe(CO)₃(COCPh)₂)]. In: Journal of Organometallic Chemistry. 2002 ; Vol. 642, No. 1-2. pp. 107-112.

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title = "Reactions of acylferrate anion [CH3COFe(CO)4]- with methyl methyl iodide and acetylenes. Synthesis of mono- and dinuclear alkenyl ketone iron complexes. X-ray structure of [NEt4][IFe(CO)3(COCPh)2)]",

abstract = "Collman's reagent [NEt4][CH3COFe(CO)4] (1) reacts with a half equivalent of methyl iodide and diphenylacetylene in acetone at 25 °C for 10 min to give [NEt4][Fe2(CO)6(μ2-CPhCPh COCH3)] (2). When the reaction of [NEt4][CH3COFe(CO)4] (1) was carried out with an excess of methyl iodide a mixture of [NEt4][IFe(CO)3(C(O)CPh)2] (3) and Fe2(CO)6μ-CPhCPhCCH3 (OCH3) (4) complexes were obtained. Complex 3 was characterized by X-ray analyses. {\textcopyright} 2002 Elsevier Science B.V. All rights reserved.",

keywords = "Alkyne, Carbonyl, Dinuclear, Iron",

author = "Abdelhay Elarraoui and Josep Ros and Ram{\'o}n Y{\'a}{\~n}ez and Xavier Solans and Merc{\`e} Font-Bardia",

year = "2002",

month = jan,

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doi = "10.1016/S0022-328X(01)01177-9",

language = "English",

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Elarraoui, A, Ros, J , Yáñez, R , Solans, X & Font-Bardia, M 2002, 'Reactions of acylferrate anion [CH₃COFe(CO)₄]^- with methyl methyl iodide and acetylenes. Synthesis of mono- and dinuclear alkenyl ketone iron complexes. X-ray structure of [NEt₄][IFe(CO)₃(COCPh)₂)]', Journal of Organometallic Chemistry, vol. 642, no. 1-2, pp. 107-112. https://doi.org/10.1016/S0022-328X(01)01177-9

Reactions of acylferrate anion [CH₃COFe(CO)₄]^- with methyl methyl iodide and acetylenes. Synthesis of mono- and dinuclear alkenyl ketone iron complexes. X-ray structure of [NEt₄][IFe(CO)₃(COCPh)₂)]. / Elarraoui, Abdelhay; Ros, Josep ; Yáñez, Ramón ; Solans, Xavier; Font-Bardia, Mercè.

In: Journal of Organometallic Chemistry, Vol. 642, No. 1-2, 01.01.2002, p. 107-112.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Reactions of acylferrate anion [CH3COFe(CO)4]- with methyl methyl iodide and acetylenes. Synthesis of mono- and dinuclear alkenyl ketone iron complexes. X-ray structure of [NEt4][IFe(CO)3(COCPh)2)]

AU - Elarraoui, Abdelhay

AU - Ros, Josep

AU - Yáñez, Ramón

AU - Solans, Xavier

AU - Font-Bardia, Mercè

PY - 2002/1/1

Y1 - 2002/1/1

N2 - Collman's reagent [NEt4][CH3COFe(CO)4] (1) reacts with a half equivalent of methyl iodide and diphenylacetylene in acetone at 25 °C for 10 min to give [NEt4][Fe2(CO)6(μ2-CPhCPh COCH3)] (2). When the reaction of [NEt4][CH3COFe(CO)4] (1) was carried out with an excess of methyl iodide a mixture of [NEt4][IFe(CO)3(C(O)CPh)2] (3) and Fe2(CO)6μ-CPhCPhCCH3 (OCH3) (4) complexes were obtained. Complex 3 was characterized by X-ray analyses. © 2002 Elsevier Science B.V. All rights reserved.

AB - Collman's reagent [NEt4][CH3COFe(CO)4] (1) reacts with a half equivalent of methyl iodide and diphenylacetylene in acetone at 25 °C for 10 min to give [NEt4][Fe2(CO)6(μ2-CPhCPh COCH3)] (2). When the reaction of [NEt4][CH3COFe(CO)4] (1) was carried out with an excess of methyl iodide a mixture of [NEt4][IFe(CO)3(C(O)CPh)2] (3) and Fe2(CO)6μ-CPhCPhCCH3 (OCH3) (4) complexes were obtained. Complex 3 was characterized by X-ray analyses. © 2002 Elsevier Science B.V. All rights reserved.

KW - Alkyne

KW - Carbonyl

KW - Dinuclear

KW - Iron

U2 - 10.1016/S0022-328X(01)01177-9

DO - 10.1016/S0022-328X(01)01177-9

M3 - Article

VL - 642

SP - 107

EP - 112

IS - 1-2

ER -